Syntheses, Structures, and Catalytic Properties of Three Copper(II) Coordination Polymers Based on 2,3,5,6-Tetrafluoro-1,4-bis(triazole-ylmethyl)benzene and Benzene Carboxylate Ligands

Tian Feng; Shen Nan; Chen Sheng-Chun; Jiang Li-Ting; Chen Qun; He Ming-Yang

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Syntheses, Structures, and Catalytic Properties of Three Copper(II) Coordination Polymers Based on 2,3,5,6-Tetrafluoro-1,4-bis(triazole-ylmethyl)benzene and Benzene Carboxylate Ligands

机译：基于2,3,5,6-四氟-1,4-双（三唑 - 基甲基）苯和苯羧酸盐配体的三种铜（II）配位聚合物的合成，结构和催化性能

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Three new mixed-ligand coordination polymers of Cu-II, namely, [Cu(Fbtx)(L1)(H2O)](n) (1), [Cu(Fbtx)(0.5)(HL2)(H2O)(2)](n) (2), and {[Cu(Fbtx)(1.5)(HL3)(H2O)]center dot H2O}(n) (3) [Fbtx = 2,3,5,6-tetrafluoro-1,4-bis(1,2,4-triazole-1-ylmethyl)benenze, H(2)L1 = terephthalic acid, H(3)L2 = trimesic acid, NaH(2)L3 = 5-sulfoisophthalic acid monosodium salt], were hydrothermally synthesized and structurally characterized by elemental analysis, IR spectra, and single-crystal and powder X-ray diffraction techniques. All the complexes have a two-dimensional (2D) coordination layer structure. Of these, 1 displays a planar 4(4)-sql structure whereas both 2 and 3 are highly undulated 6(3)-hcb nets. Moreover, their thermal stability and catalytic behaviors in the aerobic oxidation of 4-methoxybenzyl alcohol were also investigated as well. The results indicate that the benzene dicarboxylate ligands have an effective influence on the structures and catalytic properties of the resulting coordination polymers.

机译：Cu-II的三种新的混合配体配位聚合物，即[Cu（FBTX）（L1）（H 2 O）]（N）（N）（1），[Cu（FBTX）（0.5）（H12）（H 2 O）（2） ]（n）（2），和{[Cu（FBTX）（1.5）（H13）（H2O）]中心点H2O}（n）（3）[FBTX = 2,3,5,6,6-四氟-1， 4-BIS（1,2,4-三唑-1-基甲基）Benenze，H（2）L1 =对苯二甲酸，H（3）L2 = Timesic acid，NaH（2）L3 = 5-磺基苯二甲酸单钠盐]，通过元素分析，IR光谱和单晶和粉末X射线衍射技术进行水热合成和结构表征。所有复合物都具有二维（2D）配位结构。其中，1显示平面4（4）-SQL结构，而2和3是高度波动的6（3）-HCB网。此外，还研究了它们在4-甲氧基苄醇的有氧氧化中的热稳定性和催化性能。结果表明，苯二羧酸酯配体对所得配位聚合物的结构和催化性能具有有效影响。

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2019年第1期|共7页
作者
Tian Feng; Shen Nan; Chen Sheng-Chun; Jiang Li-Ting; Chen Qun; He Ming-Yang;
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作者单位

Nanjing Univ Sci &

Technol Sch Chem Engn Nanjing 210094 Jiangsu Peoples R China;

Changzhou Univ Jiangsu Key Lab Adv Catalyt Mat &

Technol Sch Petrochem Engn Changzhou 213164 Peoples R China;

Changzhou Univ Jiangsu Key Lab Adv Catalyt Mat &

Technol Sch Petrochem Engn Changzhou 213164 Peoples R China;

Changzhou Univ Jiangsu Key Lab Adv Catalyt Mat &

Technol Sch Petrochem Engn Changzhou 213164 Peoples R China;

Changzhou Univ Jiangsu Key Lab Adv Catalyt Mat &

Technol Sch Petrochem Engn Changzhou 213164 Peoples R China;

Nanjing Univ Sci &

Technol Sch Chem Engn Nanjing 210094 Jiangsu Peoples R China;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Coordination polymer; Crystal structure; Copper; Catalytic properties;

机译：协调聚合物;晶体结构;铜;催化性质;

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1. Syntheses, Structures, and Catalytic Properties of Three Copper(II) Coordination Polymers Based on 2,3,5,6-Tetrafluoro-1,4-bis(triazole-ylmethyl)benzene and Benzene Carboxylate Ligands [J] . Tian Feng, Shen Nan, Chen Sheng-Chun, Zeitschrift fur Anorganische und Allgemeine Chemie . 2019,第1期

机译：基于2,3,5,6-四氟-1,4-双（三唑 - 基甲基）苯和苯羧酸盐配体的三种铜（II）配位聚合物的合成，结构和催化性能
2. Structures and spectroscopic properties of chain polymeric complexes of copper(II) halides with 2,3,5,6-tetrafluoro-1,4-bis(2-pyridylsulfenyl)benzene and its 4-pyridylsulfenyl analogue [J] . Goodgame DML., Hitchman MA., Long NJ., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1998,第24期

机译：卤化铜（II）与2,3,5,6-四氟-1,4-双（2-吡啶硫基）苯及其4-吡啶硫基类似物的链状聚合物配合物的结构和光谱性质
3. Structures and spectroscopic properties of chain polymeric complexes of copper(II) halides with 2,3,5,6-tetrafluoro-1,4-bis(2-pyridylsulfenyl)benzene and its 4-pyridylsulfenyl analogue [J] . Goodgame DML., Hitchman MA., Long NJ., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1998,第24期

机译：卤化铜（II）与2,3,5,6-四氟-1,4-双（2-吡啶硫基）苯及其4-吡啶硫基类似物的链状聚合物配合物的结构和光谱性质
4. Synthesis, characterization, magnetic properties of cobalt coordination polymer based on 4,4'-Oxybisbenzoic acid and 1,4-bis(pyrid-4-yl)benzene [C] . Fengping Xiao, Peng Hu International Conference on Material Science, Energy and Environmental Engineering . 2017

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5. Synthesis, Structure and Catalytic Application of Silver (I) Coordination Polymers Based on 1,2,4,5-Tetra(Isopropylthio)Benzene Ligand [D] . Kakumanu, Srinija. 2017

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8. Solid State Solution Behavior of Triorganotin (IV) Derivatives Containing the2,4,6-Tris-(Triflu oromethyl)Benzene 1,4-Bis(Perfluoroisopropoxy) Tetrafluorobenzene Ligands: Crystal Molecular Structures of 2,4,6-(CF3)3C6H2Sn(C6H5)3 and 1,4-(CH3)SnOC(CF)32C6F [R] . Vij, A., Kirchmeier, R. L., Willett, R. D., 1994

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Syntheses, Structures, and Catalytic Properties of Three Copper(II) Coordination Polymers Based on 2,3,5,6-Tetrafluoro-1,4-bis(triazole-ylmethyl)benzene and Benzene Carboxylate Ligands

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