A New Heterometallic Cu-II-La-III Metal-organic Framework: Crystal Structure, Adsorption of Light Hydrocarbons and Anti-gastric Cancer Activity

Zhang Lian-Xing; Han Xia; Yang Yan; Zhang Qiu-Ning; Wang Jia; Li Zhi-Hu

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >A New Heterometallic Cu-II-La-III Metal-organic Framework: Crystal Structure, Adsorption of Light Hydrocarbons and Anti-gastric Cancer Activity

【24h】

A New Heterometallic Cu-II-La-III Metal-organic Framework: Crystal Structure, Adsorption of Light Hydrocarbons and Anti-gastric Cancer Activity

机译：一种新的异素Cu-II-LA-III金属 - 有机框架：晶体结构，轻质烃和抗胃癌活动的吸附

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The solvothermal self-assembly reaction of CuCl2, LaCl3, and H(2)tdc afforded a new heterometallic compound, namely [CuLa2(tdc)(4)(H2O)(DMA)(2)](n) (1) (H(2)tdc = thiophene-2,5-dicarboxylic acid, DMA = N,N '-dimethylacetamide). Single crystal X-ray diffraction analysis revealed that compound 1 features a 3D framework based on 1D heterometallic rod-shaped Cu-II-La-III-carboxylate chains. The porous framework of the desolvated samples (denoted as 1 ') can be easily obtained via the heat treatment process at 200 degrees C for 2 h. Gas adsorption investigations revealed that 1 ' exhibits good light hydrocarbons adsorption performance. In addition, the anticancer activities of this heterometallic complex were evaluated via the MTT assay.

机译：CuCl2，LACL3和H（2）Tdc的溶剂热自组装反应得到了一种新的杂核化合物，即[CULA2（TDC）（4）（H2O）（DMA）（2）]（1）（H （2）TDC =噻吩-2,5-二羧酸，DMA = N，N'-二甲基乙酰胺）。单晶X射线衍射分析显示，化合物1具有基于1D杂动机棒状Cu-II-La-III-羧酸壳链的3D框架。通过在200℃下通过热处理过程可以容易地获得去溶剂样品的多孔框架（表示为1'）2小时。气体吸附调查显示1'表现出良好的轻质碳氢化合物吸附性能。此外，通过MTT测定评估该杂常常核复合物的抗癌活性。

著录项

来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2018年第23期|共5页
作者
Zhang Lian-Xing; Han Xia; Yang Yan; Zhang Qiu-Ning; Wang Jia; Li Zhi-Hu;
展开▼
作者单位

Gansu Tumor Hosp Dept Digest Oncol Lanzhou Gansu Peoples R China;

Gansu Tumor Hosp Dept Digest Oncol Lanzhou Gansu Peoples R China;

Gansu Tumor Hosp Dept Digest Oncol Lanzhou Gansu Peoples R China;

Gansu Tumor Hosp Dept Digest Oncol Lanzhou Gansu Peoples R China;

Gansu Tumor Hosp Dept Digest Oncol Lanzhou Gansu Peoples R China;

Gansu Tumor Hosp Dept Digest Oncol Lanzhou Gansu Peoples R China;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Solvothermal reactions; Copper; Heterometallic compound; Light hydrocarbons; Gas adsorption;

机译：溶剂热反应;铜;杂核化合物;轻质碳氢化合物;气体吸附;

相似文献

外文文献
中文文献
专利

1. A New Heterometallic Cu-II-La-III Metal-organic Framework: Crystal Structure, Adsorption of Light Hydrocarbons and Anti-gastric Cancer Activity [J] . Zhang Lian-Xing, Han Xia, Yang Yan, Zeitschrift fur Anorganische und Allgemeine Chemie . 2018,第23期

机译：一种新的异素Cu-II-LA-III金属 - 有机框架：晶体结构，轻质烃和抗胃癌活动的吸附
2. Bifunctional (3,6)-Connected Gd(III) Metal-Organic Framework Material with Catalytic Properties for the Cyanosilylation Reaction and Anti-gastric Cancer Activity [J] . Chen Zhou-Feng, Xue Hai-Bo, Wu Lei-Ruo, Journal of cluster science . 2018,第6期

机译：双官能（3,6） - 连接Gd（III）金属 - 有机骨架材料，具有催化性能的氰基甲硅烷化反应和抗胃癌活性
3. Solvent-mediated crystal-to-crystal transformations from a cationic homometallic metal-organic framework to heterometallic frameworks [J] . Li Xinxiong, Gong Yaqiong, Zhao Huaixia, CrystEngComm . 2014,第37期

机译：溶剂介导的晶体到晶体的转变，从阳离子均金属金属有机骨架到杂金属骨架
4. Understanding the Crystal Structure of Heterometallic Metal-Organic Frameworks in Cadmium Imidazolate Framework-1 with Periodic Density Functional Theory [C] . Fajar I. Pambudi, Kristiana Fajariatr International Conference on Science and Technology . 2021

机译：理解亚咪唑酯框架框架-1中杂象金属 - 有机骨架的晶体结构，周期性密度函数理论
5. A Calorimetric Study of Light Hydrocarbon Adsorption on Metal-Organic Frameworks [D] . Barrett, Taylor 2019

机译：金属有机骨架上轻烃吸附的量热研究
6. Lanthanide Metal-Organic Frameworks with Six-Coordinated Ln(III) Ions and Free Functional Organic Sites for Adsorptions and Extensive Catalytic Activities [O] . Yu Zhu, Min Zhu, Li Xia, -1

机译：具有六配位Ln（III）离子和可吸附和广泛催化活性的自由功能性有机位点的镧系金属有机骨架
7. Synthesis, crystal structure and magnetic characterization of a series of CuII-LnIII heterometallic Ln = La, Ce, Pr, Nd and Sm) metal-organic compounds with an unusual single crystal to single crystal phase transition [O] . Díaz-Gallifa Pau, Fabelo Óscar, Cañadillas-Delgado Laura, 2015

机译：一系列具有异常单晶至单晶相变的CuII-LnIII杂金属Ln = La，Ce，Pr，Nd和Sm）金属有机化合物的合成，晶体结构和磁性表征

A New Heterometallic Cu-II-La-III Metal-organic Framework: Crystal Structure, Adsorption of Light Hydrocarbons and Anti-gastric Cancer Activity

摘要

著录项

相似文献

相关主题

期刊订阅