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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Syntheses, Characterization, and Fluorescence Properties of Four Coordination Polymers based on Double Betaine Ligands
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Syntheses, Characterization, and Fluorescence Properties of Four Coordination Polymers based on Double Betaine Ligands

机译：基于双甜菜碱配体的四种配位聚合物的合成，表征和荧光性能

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摘要

> Four novel In 3+ and Cd 2+ based 1D coordination compounds constructed by double betaine ligands were synthesized and characterized structurally and optically. They assemble into 3D supra‐molecular architectures via different stacking or entanglement of 1D zigzag shaped chains, in which C–H ··· Cl and C–H ··· O hydrogen bonding interactions play a dramatic impact. Compound 1 displays a 1D + 1D → 3D four‐connect lvt net with 4 2 · 8 4 topology. Compound 2 assembles into a 3D architecture by inclined stacking of the adjacent zigzag chains. Compound 3 displays a 2D + 2D → 3D inclined polycatenation based on the resulting 2D (6, 3) layers that constructed by 1D chains. Compound 4 displays a 3D supra‐molecular architecture based on 1D chains, which were connected via the hydrogen bonding. Meanwhile, four compounds emit in the range of visible region owing to the intra‐ligand π*→π and/or π*→n electron transition induced florescence.
机译：<摘要型=“main”> >在结构上由双甜菜碱配体构建的基于CD 3 + 和Cd 2 + / sup>的Cd 2 + / sup>在结构上和光学的特征。它们通过不同的堆叠或缠结组装到3D超分子架构，其中Z字形形状的不同堆叠或缠结，其中C-H ···... CL和C-H ···... o氢键相互作用起着戏剧性的影响。复合 1 显示1d + 1d→3d四连接Lvt网，带有4 2 · 8 4 拓扑。通过倾斜堆叠相邻的锯齿链倾斜堆叠将化合物 2 组装成3D架构。化合物 3 基于由1D链构成的所得的2D（6,3）层显示2D + 2D→3D倾斜的多粘合剂。化合物 4 基于1D链显示3D超分子结构，通过氢键连接。同时，由于配体内π*→π和/或π*→N电子转型诱导的荧光，四种化合物在可见区域的范围内发射。

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    Gai Yanli; Zhao Xueyan; Chen Yan; Liang Bing; Li Xin; Guo Xinyue; Huang Qing; Liu Lijun; Xiong Kecai;

  • 作者单位

    School of Chemistry and Materials ScienceJiangsu Normal UniversityShanghai Rd 101 221116 Xuzhou Jiangsu P. R. China;

    School of Chemistry and Materials ScienceJiangsu Normal UniversityShanghai Rd 101 221116 Xuzhou Jiangsu P. R. China;

    School of Chemistry and Materials ScienceJiangsu Normal UniversityShanghai Rd 101 221116 Xuzhou Jiangsu P. R. China;

    School of Chemistry and Materials ScienceJiangsu Normal UniversityShanghai Rd 101 221116 Xuzhou Jiangsu P. R. China;

    School of Chemistry and Materials ScienceJiangsu Normal UniversityShanghai Rd 101 221116 Xuzhou Jiangsu P. R. China;

    School of Chemistry and Materials ScienceJiangsu Normal UniversityShanghai Rd 101 221116 Xuzhou Jiangsu P. R. China;

    School of Chemistry and Materials ScienceJiangsu Normal UniversityShanghai Rd 101 221116 Xuzhou Jiangsu P. R. China;

    School of Chemistry and Materials ScienceJiangsu Normal UniversityShanghai Rd 101 221116 Xuzhou Jiangsu P. R. China;

    School of Chemistry and Materials ScienceJiangsu Normal UniversityShanghai Rd 101 221116 Xuzhou Jiangsu P. R. China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

    In 3+ /Cd 2+ coordination polymers; Indium; Cadmium; Double betaine ligands; Fluorescence properties;

    机译：在3+ / CD 2+配位聚合物;铟;镉;双甜菜碱配体;荧光性质;

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