Formation of amidoberyllates from beryllium and alkali metals in liquid ammonia

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Formation of amidoberyllates from beryllium and alkali metals in liquid ammonia

机译：从液氨中的铍和碱金属形成氨咪唑类化合物

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Beryllium metal was dissolved in liquid ammonia at ambient temperature through addition of alkali metals. Thereby, the amidoberyllates Cs[Be(NH2)(3)], [Na-4(NH2)(2)][Be(NH2)(4)] and K-4[Be2O(NH2)(4)][Be(NH2)(3)](2) were isolated and structurally characterized via single crystal X-ray diffraction. In the case of Li we were able to synthesize Be(NH2)(2) at ambient temperature. We present the first example of a [Be(NH2)(4)](2-) anion as well as the first oxyamidoberyllate anion [Be2O(NH2)(4)](2-).

机译：通过加入碱金属，在环境温度下溶解在液态氨中的铍金属。由此，氨基咪唑类化合物Cs [是（NH2）（3）]，[Na-4（NH 2）（2）] [是（NH 2）（4）]和K-4 [BE2O（NH2）（4）] [是（NH 2）（3）]（2）被分离并通过单晶X射线衍射进行结构表征。在Li的情况下，我们能够在环境温度下合成（NH2）（2）。我们介绍了[是（NH2）（4）]（2-）阴离子以及第一个氧中氧化物阴离子[BE2O（NH2）（4）]（2-）的第一个例子。

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2020年第5期|共7页
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正文语种 eng
中图分类化学;
关键词
alkali metal; ammonia; beryllate; beryllium;

机译：碱金属;氨;铍;铍;

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1. Formation of amidoberyllates from beryllium and alkali metals in liquid ammonia [J] . Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2020,第5期

机译：从液氨中的铍和碱金属形成氨咪唑类化合物
2. Reductive activation of arenas 21. Reaction of products of two-electron reduction of arenecarbonitriles by alkali metals in liquid ammonia with bromo- and dibromoalkanes [J] . T.A.Vaganova, E.V.Panteleeva, P.S.Yuferov Russian Chemical Bulletin . 2006,第6期

机译：竞技场的还原性活化21.液态氨中碱金属的两电子还原芳烃的产物与溴代和二溴代烷烃的反应
3. Fission of As-As bonds in elemental arsenic by alkali metals in liquid ammonia. Preparation of dialkyl and trialkyl arsines [J] . Brandsma L., Van der Kerk-Van Hoof ACHTM., Bjorlo O. Phosphorus, Sulfur, and Silicon and the Related Elements . 2000,第0期

机译：液态氨中的碱金属会裂解元素砷中的As-As键。二烷基和三烷基a的制备
4. LIQUID DENSITY OF ALKALI METAL IODIDE + AMMONIA SOLUTIONS [C] . Daisuke Tomida, Quanxi Bao, Chiaki Yokoyama The Ninth Asian thermophysical properties conference (ATPC 2010). . 2010

机译：碱金属碘化物+氨溶液的液体密度
5. LIQUID THEORY OF THE ALKALI-METALS: PART I. THE SIGNIFICANT LIQUID STRUCTURE THEORY APPLIED TO THE THERMODYNAMIC PROPERTIES OF THE ALKALI-METALS. PART II. THE SIGNIFICANT LIQUID STRUCTURE THEORY APPLIEDTO THE SURFACE TENSION OF THE ALKALI-METALS. PART II [D] . HSU, CHEN CHAO. 1972

机译：碱金属的液体理论：第一部分，适用于碱金属热力学性质的重要液体结构理论。第二部分重要的液体结构理论适用于碱金属的表面张力。第二部分
6. Speciation of Be2+ in acidic liquid ammonia and formation of tetra- and octanuclear beryllium amido clusters [O] . Matthias Müller, Antti J. Karttunen, Magnus R. Buchner 2020

机译：Be2 +在酸性液氨中的形态和四核铍的形成酰胺簇
7. Organic Syntheses with Alkali Hydroxide in Liquid Ammonia. III. N-Benzylation of Glycine Derivatives with Alkali Hydroxide in Liquid Ammonia. [O] . Ryuzo Asami, Kotaro Shimo, Ritsuro Tada 1957

机译：有机合成液氨酸碱氢氧化物。 III。甘氨酸衍生物与碱氢氧化物在液氨中的N-苄化化。

Formation of amidoberyllates from beryllium and alkali metals in liquid ammonia

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