Synthesis and crystal structure of the copper silylamide cluster compound [Cu9{MesSi(NPh)3}2 (PhCO2)3]

UweMorgenstern; ChristophWagner; KurtMerzweiler

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Synthesis and crystal structure of the copper silylamide cluster compound [Cu9{MesSi(NPh)3}2 (PhCO2)3]

机译：铜甲硅烷基团聚合物化合物的合成和晶体结构[CU9 {MESSI（NPH）3} 2（PHCO2）3]

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The trifunctional silylamine MesSi(NHPh)3 (Mes: 2,4,6-trimethylphenyl) was prepared by standard methods from MesSiCl3 and LiNHPh. Lithiation of MesSi(NHPh)3 and subsequent reaction with copper(I) benzoate afforded the nonanuclear cluster complex [Cu9{MesSi(NPh)3}2 (PhCO2)3]·2toluene. The cluster core consists of three copper atoms which are coordinated almost linearly by the nitrogen atoms of two adjacing MesSi(NPh)3 units. Additionally, each of the silylamide nitrogen atoms is connected to a peripheral copper atom and the peripheral copper atoms are linked by μ2-κ(O,O′) bridging benzoate groups. The observed Cu–N distances are in the range 189.6(4)–196.7(3) pm.

机译：通过来自Messicl3和LinHPH的标准方法制备三官能甲硅烷酰胺Messi（NHPH）3（MES：2,4,4,6-三甲基苯基）。梅西（NHPH）3和随后与铜（I）苯甲酸酯的反应，得到非核簇复合物[CU9 {MESSI（NPH）3} 2（PHCO2）3]·2Toluene。聚类核心由三个铜原子组成，其几乎线性地由两个邻接梅西（NPH）3个单位的氮原子进行协调。另外，每种甲硅烷酰胺氮原子连接到外周铜原子，外周铜原子通过桥接苯甲酸酯基团的μ2-κ（O，O'）连接。观察到的Cu-n距离在189.6（4）-196.7（3）PM范围内。

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2018年第11期|共5页
作者
UweMorgenstern; ChristophWagner; KurtMerzweiler;
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作者单位

Institut für Chemie Naturwissenschaftliche Fakult?t II Universit?t Halle Kurt-Mothes-Str. 2 06120 Halle Germany;

Institut für Chemie Naturwissenschaftliche Fakult?t II Universit?t Halle Kurt-Mothes-Str. 2 06120 Halle Germany;

Institut für Chemie Naturwissenschaftliche Fakult?t II Universit?t Halle Kurt-Mothes-Str. 2 06120 Halle Germany;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
benzoate; cluster; complex; copper; silylamide; X-ray;

机译：苯甲酸盐;簇;复合物;铜;甲硅烷基;X射线;

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Synthesis and crystal structure of the copper silylamide cluster compound [Cu9{MesSi(NPh)3}2 (PhCO2)3]

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