A Mn(II) coordination polymer from a polycarboxylate-containing ligand: synthesis, structural characterization, and properties

Xiao-HongZhu; Xiao-ChunCheng; Yun-HuaQian

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A Mn(II) coordination polymer from a polycarboxylate-containing ligand: synthesis, structural characterization, and properties

机译：来自含有多羧酸盐配体的Mn（II）配位聚合物：合成，结构表征和性质

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The neutral, four-fold protonated pyridine-3,5-dicarbox(3,5-dicarboxylatoanilide) (H4L) reacts with Mn(II) salts under hydrothermal conditions to yield a new complex: [Mn2(L)(H2O)2]·H2O (1), which has been characterized by single crystal X-ray diffraction, infrared spectroscopy, and elemental and thermogravimetric analyses. Complex 1 exhibits a binodal (4,8)-connected 3D framework with flu (412.612.84)(46)2 topology. The magnetic properties of 1 were investigated.

机译：中性的四折叠质子化吡啶-3,5-二羧盒（3,5-二羧酸）（H4L）与水热条件下的Mn（II）盐反应，得到新的复合物：[Mn2（L）（H2O）2] ·H2O（1），其特征在于单晶X射线衍射，红外光谱和元素和热重分析。复合体1展示了与流感（412.612.84）（46）2拓扑的二进制（4,8）连接的3D框架。研究了1的磁性。

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来源
《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2017年第12期|共4页
作者
Xiao-HongZhu; Xiao-ChunCheng; Yun-HuaQian;
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作者单位

Jiangsu Provincial Key Laboratory of Palygorskite Science and Applied Technology Huaiyin Institute of Technology Huaian 223003 P.R. China;

Jiangsu Provincial Key Laboratory of Palygorskite Science and Applied Technology Huaiyin Institute of Technology Huaian 223003 P.R. China;

Jiangsu Provincial Key Laboratory of Palygorskite Science and Applied Technology Huaiyin Institute of Technology Huaian 223003 P.R. China;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
coordination polymer; magnetic interaction; Mn(II); structural characterization;

机译：协调聚合物;磁相互作用;Mn（II）;结构表征;

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A Mn(II) coordination polymer from a polycarboxylate-containing ligand: synthesis, structural characterization, and properties

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