Synthesis, crystal structure, and photoluminescence of a lithium isothiocyanate compound with 18-crown-6

ShanFu; BoFu; ZhenZhao; XiLiu

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Synthesis, crystal structure, and photoluminescence of a lithium isothiocyanate compound with 18-crown-6

机译：用18-Crown-6的锂异硫氰酸酯化合物的合成，晶体结构和光致发光

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The investigation of the supramolecular interactions between the lithium isothiocyanate salt and 18-crown-6 (18C-6) in commercial tetrahydrofuran leads to the formation of a lithium compound, LiNCS(H2O)(18C-6) (1). In the crystal structure the asymmetric unit contains two similar LiNCS(H2O)(18C-6) molecules. Solid-state photoluminescence experiments have shown that compound 1 emits violet luminescence, and its possible emission mechanism was investigated in detail based on theoretical calculations.

机译：在商业四氢呋喃中锂异硫氰酸酯盐和18℃-6（18C-6）之间的超分子相互作用导致形成锂化合物，LINCs（H 2 O）（18C-6）（1）。在晶体结构中，不对称单元包含两种类似的含锌（H2O）（18C-6）分子。固态光致发光实验表明，化合物1发射紫发光，并根据理论计算详细研究了其可能的排放机制。

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来源
《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2018年第2期|共5页
作者
ShanFu; BoFu; ZhenZhao; XiLiu;
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作者单位

Chongqing Key Laboratory of Inorganic Functional Materials College of Chemistry Chongqing Normal University Chongqing 401331 P.R. China;

Chongqing Key Laboratory of Inorganic Functional Materials College of Chemistry Chongqing Normal University Chongqing 401331 P.R. China;

Chongqing Key Laboratory of Inorganic Functional Materials College of Chemistry Chongqing Normal University Chongqing 401331 P.R. China;

Chongqing Key Laboratory of Inorganic Functional Materials College of Chemistry Chongqing Normal University Chongqing 401331 P.R. China;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
crown ether; crystal structure; isothiocyanate; lithium; photoluminescence;

机译：冠醚;晶体结构;异硫氰酸酯;锂;光致发光;

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1. Synthesis, crystal structure, and photoluminescence of a lithium isothiocyanate compound with 18-crown-6 [J] . ShanFu, BoFu, ZhenZhao, Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2018,第2期

机译：用18-Crown-6的锂异硫氰酸酯化合物的合成，晶体结构和光致发光
2. Synthesis, Crystal Structure, and Photoluminescence of a Lithium Perchlorate Complex with 18-Crown-6 [J] . Jian Y. -F., Fu B., Fu S., Journal of structural chemistry . 2019,第7期

机译：具有18℃-6的高氯酸锂络合物的合成，晶体结构和光致发光
3. SYNTHESIS,CRYSTAL STRUCTURE,AND PHOTOLUMINESCENCE OF A LITHIUM PERCHLORATE COMPLEX WITH 18-CROWN-6 [J] . Y.-F.Jian, B.Fu, S.Fu Журнал струκтурной химии . 2019,第7期

机译：具有18℃-6的高氯酸锂络合物的合成，晶体结构和光致发光
4. Photoluminescence and Features of the Defective Structure of Nominally Pure Lithium Niobate Crystals [C] . Maxim Smirnov, Nikolay Sidorov, Natalya Teplyakova, Asia School-Conference on Physics and Technology of Nanostructured Materials . 2020

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5. Templating the synthesis of compound semiconductor nanostructures using microemulsions and lyotropic liquid crystals. [D] . Karanikolos, Georgios. 2005

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机译：高效合成晶体结构和光致发光特性深红色发光的Ba2GdTaO6：Mn4 +荧光粉
7. Synthesis and crystal structure of lithium phosphorus nitride Li7PN4. The first compound containing isolated PN4-tetrahedra [O] . Schnick Wolfgang, Lücke Jan 1990

机译：锂磷氮化物Li7pN4的合成与晶体结构。第一种含有pN4-四面体的化合物

Synthesis, crystal structure, and photoluminescence of a lithium isothiocyanate compound with 18-crown-6

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