C-H perfluorobutylation of bislactam dyes

Xu Yuchun; Wang Yazhou; Liao Hailiang; Guo Yanjun; Xue Xiang; Yang Xinru; Yang Yinghe; Sun Jian; Li Zhengke; Yue Wan

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C-H perfluorobutylation of bislactam dyes

机译：双酰胺胺染料的C-H Perflar脱粒化

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A series of mono-perfluorobutylated and di-perfluorobutylated bislactam dyes have been synthesized using a C-H functionalization. Single crystal analysis shows that the intermolecular fluorophobic interaction induce unique self-organized architectures by the perfluorobutyl chain on the core of the bislactam dye. Their opto-electronic properties have been investigated, and increased electron affinities are observed for these perfluorobutylated bislactam dyes.

机译：通过C-H官能化合成了一系列单氟丁基化的和二 - 全氟丁基的双LACTAM染料。单晶分析表明，分子间荧光虫相互作用通过本液体染料的核心上的全氟丁基链诱导独特的自组织架构。已经研究了它们的光电性质，并观察到这些全氟化丁胺的双酰胺染料的增加的电子亲和力。

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来源
《Dyes and Pigments》 |2019年第2019期|共6页
作者
Xu Yuchun; Wang Yazhou; Liao Hailiang; Guo Yanjun; Xue Xiang; Yang Xinru; Yang Yinghe; Sun Jian; Li Zhengke; Yue Wan;
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作者单位

Sun Yat Sen Univ Minist Educ Sch Mat Sci &

Engn Key Lab Polymer Composite &

Funct Mat Guangzhou 510275 Guangdong Peoples R China;

Sun Yat Sen Univ Minist Educ Sch Mat Sci &

Engn Key Lab Polymer Composite &

Funct Mat Guangzhou 510275 Guangdong Peoples R China;

Sun Yat Sen Univ Minist Educ Sch Mat Sci &

Engn Key Lab Polymer Composite &

Funct Mat Guangzhou 510275 Guangdong Peoples R China;

Sun Yat Sen Univ Minist Educ Sch Mat Sci &

Engn Key Lab Polymer Composite &

Funct Mat Guangzhou 510275 Guangdong Peoples R China;

Sun Yat Sen Univ Minist Educ Sch Mat Sci &

Engn Key Lab Polymer Composite &

Funct Mat Guangzhou 510275 Guangdong Peoples R China;

Sun Yat Sen Univ Minist Educ Sch Mat Sci &

Engn Key Lab Polymer Composite &

Funct Mat Guangzhou 510275 Guangdong Peoples R China;

Sun Yat Sen Univ Minist Educ Sch Mat Sci &

Engn Key Lab Polymer Composite &

Funct Mat Guangzhou 510275 Guangdong Peoples R China;

Sun Yat Sen Univ Minist Educ Sch Mat Sci &

Engn Key Lab Polymer Composite &

Funct Mat Guangzhou 510275 Guangdong Peoples R China;

Sun Yat Sen Univ Minist Educ Sch Mat Sci &

Engn Key Lab Polymer Composite &

Funct Mat Guangzhou 510275 Guangdong Peoples R China;

Sun Yat Sen Univ Minist Educ Sch Mat Sci &

Engn Key Lab Polymer Composite &

Funct Mat Guangzhou 510275 Guangdong Peoples R China;

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正文语种 eng
中图分类染料及中间体工业;颜料工业;
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1. C-H perfluorobutylation of bislactam dyes [J] . Xu Yuchun, Wang Yazhou, Liao Hailiang, Dyes and Pigments . 2019,第期

机译：双酰胺胺染料的C-H Perflar脱粒化
2. Visible Light-Catalyzed Benzylic C-H Bond Chlorination by a Combination of Organic Dye (Acr(+)-Mes) and N-Chlorosuccinimide [J] . Xiang Ming, Zhou Chao, Yang Xiu-Long, The Journal of Organic Chemistry . 2020,第14期

机译：通过有机染料（ACR（+） - MES）和N-氯琥珀酰亚胺的组合可见光催化苄基C-H键氯化
3. beta-AlkenylBODIPY Dyes: Regioselective Synthesis via Oxidative C-H Olefination, Photophysical Properties, and Bioimaging Studies [J] . Wang Jun, Li Yongxin, Gong Qingbao, The Journal of Organic Chemistry . 2019,第9期

机译：β-链烯基二十颗染料：通过氧化C-H烯烃，光性特性和生物分析研究的区域选择性合成
4. Catalytic Stereoselective Benzylic C-H Functionalizations by Oxidative C-H Activation and Organocatalysis [C] . Montse Guiteras Capdevila, Fides Benfatti, Luca Zoli European Symposium on Organic Chemistry . 2009

机译：催化立体选择性苄基C-H官能化氧化C-H活化与有机成分
5. Copper-Mediated Oxidative Decarboxylative Coupling Reactions: Trifluoromethylation of Heteroarene C-H bonds with Trifluoroacetic Acid as the CF3 Source and C-H Arylation of Benzoxazoles with Benzoic Acids [D] . Ju, Lin 2015

机译：铜介导的氧化脱羧偶联反应：以三氟乙酸为CF3源的杂芳烃C-H键的三氟甲基化和苯并恶唑与苯甲酸的C-H芳基化
6. Synthesis of Novel 36-Dithienyl Diketopyrrolopyrrole Dyes by Direct C-H Arylation [O] . Amsalu Efrem Yemene, Vishwesh Venkatraman, David Moe Almenningen, 2020

机译：直接C-H芳基化合成新型36-二噻吩基二酮基吡咯并吡咯染料
7. Radical C-H Arylation of the BODIPY Core with Aryldiazonium Salts: Synthesis of Highly Fluorescent Red-Shifted Dyes [O] . Verbelen Bram, Boodts Stijn, Hofkens Johan, 2015

机译：BODIPY核心与芳基重氮盐的自由基C-H芳基化：高荧光红移染料的合成
8. Homolytic bond dissociation energies for C-H bonds adjacent to sulfur and aromatic moieties: The effects of substituents of C-H bond strengths of the benzylic positions in coal model compounds [R] . Alnajjar, M. S., Franz, J. A., Gleicher, G. J., 1993

机译：与硫和芳香族部分相邻的C-H键的均聚键解离能：煤模型化合物中苄基位置的C-H键强度取代基的影响

C-H perfluorobutylation of bislactam dyes

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