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Co-Extraction during Reactive Extraction of Phenylalanine using Aliquat 336:Interfacial Mass Transfer

机译:使用Aliquat 336:界面传质反应萃取苯丙氨酸过程中的共萃取

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Reactive liquid-Liquid extraction can be used to separate hydrophilic fermentation products that would not otherwise partition into nonpolar solvents.However,during extraction of the target solute other compounds present on the extraction hddium will also react with the ion exchange reagent and are thus co-extracted.In this study the effect of co-extraction on the interfacial flux of the target solute phenylalanine has been investigated fro reactive extraction usign Aliquat 336 The effect of co-extracting compounds has been included in a new interfacial flux balance and experimental results reveal the the interfacial concentration s are equal to the final equilibrium conditions of the system Using this information a simple mass transfer model has been developed from which film mass transfer coefficients may be determined Co-extraction of other compounds present in the feed was found to reduce the interfacial flux of the target solute by reducing the driving force.Co-extraction did not affect the value of thesoulte to the interface.Eztraction from a multicom-ponent fermentation broth resulted in a ceduced flux which arises from a multicom-ponent fermentation broth resulted in a reduced flux,which arise from a reduction in the driving force caused by high levels of co-extraction.Furthermore,the flux was also reduced as the result of a mass transfer resistance caused by soluble surface-axxtive compounds present on the fermentation broth adsorbing the othe interface The biomass associated with the fermentation broth was also found to reduce the solute flux,and it is believed that thsi is due to blockage of the interfacial area.
机译:反应性液-液萃取可用于分离亲水发酵产物,否则它们不会分配到非极性溶剂中。但是,在目标溶质萃取过程中,萃取the中存在的其他化合物也会与离子交换试剂发生反应,因此会共同在这项研究中,使用Aliquat 336进行了反应萃取,研究了共萃取对目标溶质苯丙氨酸的界面通量的影响。共萃取化合物的作用已包含在新的界面通量平衡中,实验结果表明界面浓度s等于系统的最终平衡条件使用此信息,我们开发了一个简单的传质模型,可以从该模型确定膜的传质系数,发现进料中存在的其他化合物的共萃取可降低界面质量通过降低驱动力实现目标溶质的通量多组分发酵液的引出导致了一定的通量,而多组分发酵液的引出导致了通量的减少,通量降低了,高通量引起的驱动力降低了。此外,通量也降低了,这是由于发酵液中存在的可溶性表面吸附性化合物吸附了其他界面而引起的传质阻力所致。还发现与发酵液相关的生物质可以减少溶质。认为这是由于界面区域的阻塞。

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