A model-based precipitation study of copper-based catalysts

Hartig Martin A. J.; Peukert Wolfgang; Jacobsen Nikolas; Leuthold Alexander

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A model-based precipitation study of copper-based catalysts

机译：基于模型的铜基催化剂的沉淀研究

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Numerical methods of particle technology are used to model the formation of catalyst precursors with the purpose to control disperse properties. A multicomponent and multiphase population balance model is applied to the precipitation of catalyst precursors in a T-mixer. Copper precursors are chosen to be investigated in detail as a basis for catalysts with a broad range of applications such as in methanol synthesis, water-gas shift and hydrogenation reactions. The simulations results could be validated by ex situ measurements such as the pH of the suspension, the solid dry weight of the precipitate, and the yield. Simulations show that dissociation reactions of copper and carbonate species in water control significantly the formation of Georgeite. Consumption of the copper component by solid formation can be controlled in a range of 20-100% by the adjustment of the pH of the copper nitrate reactant solution. (c) 2015 American Institute of Chemical Engineers AIChE J, 61: 2104-2116, 2015

机译：颗粒技术的数值方法被用来对催化剂前体的形成进行建模，以控制分散性能。将多组分和多相种群平衡模型应用于T型混合器中催化剂前体的沉淀。选择铜前体进行详细研究，以作为具有广泛应用领域的催化剂的基础，例如在甲醇合成，水煤气变换和氢化反应中的应用。模拟结果可以通过异位测量来验证，例如悬浮液的pH值，沉淀的固体干重和收率。模拟表明，水中铜和碳酸盐物种的离解反应显着控制了水母的形成。通过调整硝酸铜反应物溶液的pH，可以将由于固体形成而引起的铜成分的消耗控制在20〜100％的范围内。（c）2015年美国化学工程师学会AIChE J，61：2104-2116，2015

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《AIChE Journal》 |2015年第7期|共13页
作者
Hartig Martin A. J.; Peukert Wolfgang; Jacobsen Nikolas; Leuthold Alexander;
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正文语种 eng
中图分类化学工业;
关键词
catalyst preparation; precursor chemistry; methanol synthesis; population balance; mixing;

机译：催化剂制备;前体化学;甲醇合成;种群平衡;混合;

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1. A model-based precipitation study of copper-based catalysts [J] . Hartig Martin A. J., Peukert Wolfgang, Jacobsen Nikolas, AIChE Journal . 2015,第7期

机译：基于模型的铜基催化剂的沉淀研究
2. Understanding the generation of methanol synthesis and water gas shift activity over copper-based catalysts - A spatially resolved experimental kinetic study using steady and non-steady state operation under CO/CO2/H-2 feeds [J] . Wilkinson S. K., van de Water L. G. A., Miller B., Journal of Catalysis . 2016,第Null期

机译：了解铜基催化剂上甲醇合成的产生和水煤气转换活性-在CO / CO2 / H-2进料下使用稳态和非稳态操作进行空间分辨的实验动力学研究
3. Elucidating the mechanism and active site of the cyclohexanol dehydrogenation on copper-based catalysts: A density functional theory study [J] . Wang Ziyun, Liu Xinyi, Rooney D. W., Surface Science . 2015,第octa期

机译：阐明铜基催化剂上环己醇脱氢的机理和活性部位：密度泛函理论研究
4. Kinetic Studies of the Vapour Phase Hydrogenolysis of Methyl Formate to Methanol on Copper-Based Catalysts [C] . X. Huang, J. W. Evans, M.S. Wainwright, Asia-Pacific Congress on Catalysis . 2003

机译：铜基催化剂对甲醇甲酯气相氢化的动力学研究
5. Engineering Copper-Based Catalysts for Electrochemical CO2 Reduction to C2 Products [D] . Asif, Sayma. 2021

机译：工程铜基催化剂用于电化学二氧化碳还原成C2产物
6. PROMETHEUS: A Copper-Based Polymetallic Catalyst for Automotive Applications. Part II: Catalytic Efficiency an Endurance as Compared with Original Catalysts [O] . Iakovos Yakoumis, Εkaterini Polyzou, Anastasia Maria Moschovi 2021

机译：Prometheus：用于汽车应用的铜基多金属催化剂。第二部分：与原始催化剂相比催化效率是耐久性
7. Combined EXAFS, XRD, DRIFTS, and DFT study of nano copper-based catalysts for CO2Hydrogenation [O] . Bersani Marco, Gupta Kalyani, Mishra Abhishek Kumar, 2016

机译：结合EXAFS，XRD，DRIFTS和DFT研究纳米铜基催化剂用于CO2加氢

A model-based precipitation study of copper-based catalysts

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