Synthesis and structural characterization of a novel polymeric praseodymium(III) complex with a new flexible double betaine

Mao JG.; Ni JZ.; Zhang HJ.; Mak TCW.; Wu HT.

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Synthesis and structural characterization of a novel polymeric praseodymium(III) complex with a new flexible double betaine

机译：新型柔性双甜菜碱的新型聚合物镨（III）复合物的合成与结构表征

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A novel polymeric Pr(III) complex with a new double betaine, namely [{Pr(L-1)(1.5)(H2O)(2)}(n)] [ClOli4]3(n). nH(2)O (1) (L-1= 1,4-diazoniobicyclo[2,2,2]octane- 1,4-dipropionate), has been synthesized and characterized by X-ray analysis. In the title complex, the Pr(III) atom is nine-coordinated by seven oxygen atoms from five L-1 ligands and two aqua ligands. Each pair of adjacent praseodymium(III) atoms is linked by a pair of mu(3) chelating and bridging carboxylate groups, thus forming an infinite metal metal chain running parallel to the a direction, and such chains are cross-linked by flexible backbones of L-1 ligands into a three-dimensional network with the perchlorate anions and lattice water molecules accommodated in the interstitial space. The title complex crystallizes in the monoclinic space group P2(1)/n with a = 8.085(2), b = 14.316(3), c = 29.775(6) Angstrom, beta = 103.04(3)degrees and Z = 4. [References: 16]

机译：一种具有新的双甜菜碱的新型聚合物PR（III）复合物，即[{Pr（L-1）（1.5）（1.5）（H 2 O）（2）}（N）] [Cloli4] 3（n）。 NH（2）O（1）（L-1 = 1,4-二氮杂双环[2,2,2]辛烷-1,4-二丙酸盐）已经合成，其特征在于X射线分析。在标题复合物中，PR（III）原子由来自五个L-1配体和两个Aqua配体的七个氧原子为9。每对相邻的镨（III）原子通过一对μ（3）螯合和桥接羧酸盐基团连接，从而形成平行于方向的无限金属金属链，并且这种链通过柔性骨架交联 L-1配体进入三维网络，其具有高氯酸盐阴离子和容纳在间隙空间的晶格水分子。标题复合物在单斜斜面基团P2（1）/ N中结晶，A = 8.085（2），B = 14.316（3），C = 29.775（6）埃，β= 103.04（3）度和Z = 4。 [参考：16]

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来源
《Journal of chemical crystallography》 |1998年第3期|共7页
作者
Mao JG.; Ni JZ.; Zhang HJ.; Mak TCW.; Wu HT.;
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作者单位

Chinese Univ Hong Kong Dept Chem Shatin NT Hong Kong.;

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原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
Crystal structure; Coordination polymer; Praseodymium(iii) carboxylate complex; Double betaine; Crystal-structures; Ligands; Sm;

机译：晶体结构;配位聚合物;镨（III）羧酸盐复合物;双甜菜碱;晶体结构;配体;SM;

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1. Synthesis and structural characterization of a novel polymeric praseodymium(III) complex with a new flexible double betaine [J] . Mao JG., Ni JZ., Zhang HJ., Journal of chemical crystallography . 1998,第3期

机译：新型柔性双甜菜碱的新型聚合物镨（III）复合物的合成与结构表征
2. Lanthanide coordination polymers with dicarboxylate-like ligands: crystal structures of polymeric lanthanum(III) and terbium(III) complexes with flexible double betaines [J] . Jiang-Gan Mao, Hong-Jie Zhang, Jia-Zuan Ni, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1999,第10期

机译：具有二羧酸盐样配体的镧系配位聚合物：具有柔性双甜菜碱的聚合镧（III）和ter（III）配合物的晶体结构
3. 1,2,4-Diazaphospholide complexes of lanthanum(III), cerium(III), neodymium(III), praseodymium(III), and samarium(III): synthesis, X-ray structural characterization, and magnetic susceptibility studies [J] . Zhao Minggang, Wang Lixia, Li Pangpang, Dalton transactions: An international journal of inorganic chemistry . 2016,第27期

机译：镧（III），铈（III），钕（III），ase（III）和sa（III）的1,2,4-二氮杂磷化物配合物：合成，X射线结构表征和磁化率研究
4. Synthesis and Structural Characterization of New Dithiocarbamate Complexes From Sb(III) and Bi(III) [C] . Nur Amirah Jamaluddin, Ibrahim Baba UKM FST Postgraduate Colloquium . 2013

机译：来自SB（III）和BI（III）的新二硫代氨基磺酸酯复合物的合成与结构表征
5. Synthesis and structural characterization of metal complexes of some double-betaine and N,N'-dioxide ligands. [D] . Zhang, Lin-Ping. 2003

机译：一些双甜菜碱和N，N'-二氧化物配体的金属配合物的合成和结构表征。
6. Cyclometalated Ir(III) Complex as a Metalloligandand a Selective Cu(II) Sensor: Synthesis and Structural Characterizationof a Heterometallic Tetranuclear Ir(III)/Cu(II) Complex [O] . Vadapalli Chandrasekhar, *, Bani Mahanti, 2018

机译：金属配体的环金属化Ir（III）配合物和选择性Cu（II）传感器：合成与结构表征金属四核Ir（III）/ Cu（II）配合物的合成
7. SYNTHESIS, SPECTRAL CHARACTERIZATION AND ANTIFUNGAL STUDIES ON LANTHANUM (III) AND PRASEODYMIUM (III) COMPLEXES WITH N2O2DIAZADIOXAMACROCYCLES [O] . Priti Tripathi, Akhilesh Kumar Srivastava, Om Prakash Pandey, 2020

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8. Tetradecker Metallacarborane Sandwiches: Synthesis via Double-Decker Stacking andStructural Characterization of Co-Co-Co, Co-Ni-Co, and Co-Ru-Co Complexes [R] . Piepgrass, K. W., Meng, X., Holscher, M., 1992

机译：Tetradecker metallacarborane三明治：通过双层堆叠合成Co-Co-Co，Co-Ni-Co和Co-Ru-Co配合物的结构表征

Synthesis and structural characterization of a novel polymeric praseodymium(III) complex with a new flexible double betaine

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