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Current and emerging environmentally-friendly systems for fouling control in the marine environment.

机译:当前和新兴的环保系统,用于海洋环境中的结垢控制。

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Following the ban in 2003 on the use of tributyl-tin compounds in antifouling coatings, the search for an environmentally-friendly alternative has accelerated. Biocidal TBT alternatives, such as diuron and Irgarol 1051Reg., have proved to be environmentally damaging to marine organisms. The issue regarding the use of biocides is that concerning the half-life of the compounds which allow a perpetuation of the toxic effects into the marine food chain, and initiate changes in the early stages of the organisms' life-cycle. In addition, the break-down of biocides can result in metabolites with greater toxicity and longevity than the parent compound. Functionalized coatings have been designed to repel the settlement and permanent attachment of fouling organisms via modification of either or both surface topography and surface chemistry, or by interfering with the natural mechanisms via which fouling organisms settle upon and adhere to surfaces. A large number of technologies are being developed towards producing new coatings that will be able to resist biofouling over a period of years and thus truly replace biocides as antifouling systems. In addition urgent research is directed towards the exploitation of mechanisms used by living organisms designed to repel the settlement of fouling organisms. These biomimetic strategies include the production of antifouling enzymes and novel surface topography that are incompatible with permanent attachment, for example, by mimicking the microstructure of shark skin. Other research seeks to exploit chemical signals and antimicrobial agents produced by diverse living organisms in the environment to prevent settlement and growth of fouling organisms on vulnerable surfaces. Novel polymer-based technologies may prevent fouling by means of unfavourable surface chemical and physical properties or by concentrating antifouling compounds around surfaces.Digital Object Identifier http://dx.doi.org/10.1016/j.biotechadv.2013.09.002
机译:继2003年禁止在防污涂料中使用三丁基锡化合物后,对环境友好型替代品的搜寻加速了。事实证明,杀虫剂TBT替代品(如diuron和Irgarol 1051Reg。)对海洋生物具有环境破坏作用。与杀生物剂的使用有关的问题是与化合物的半衰期有关,该半衰期可以使毒性作用长期存在于海洋食物链中,并在生物生命周期的早期阶段引发变化。另外,杀生物剂的分解可导致代谢产物比母体化合物具有更大的毒性和寿命。已设计了功能化涂层,以通过改变表面形貌和表面化学或两者,或者通过干扰污垢生物沉降并粘附在表面上的自然机制,来阻止污垢生物的沉降和永久附着。正在开发大量技术来生产新型涂料,这些涂料将能够在几年内抵抗生物污损,从而真正地将生物杀伤剂替代为防污系统。另外,紧迫的研究针对利用被设计用来排斥结垢生物沉降的活生物体使用的机制。这些仿生策略包括防污酶的产生和与永久附着不兼容的新型表面形貌,例如,通过模仿鲨鱼皮的微观结构。其他研究试图利用环境中各种活生物体产生的化学信号和抗菌剂,以防止污垢生物在脆弱表面上的沉降和生长。基于聚合物的新技术可能会通过不利的表面化学和物理特性或在表面周围集中防污化合物来防止结垢。数字对象标识符http://dx.doi.org/10.1016/j.biotechadv.2013.09.002

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