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An elaborate sensor system based on conducting polymer-oligosaccharides in hydrogel and the formation of inclusion complexes

机译:基于水凝胶中的导电聚合物 - 寡糖的精心传感器系统和包合物的形成

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In this study, electrically conductive materials composed of carboxylated polypyrrole (PPy(COOH)) and nontoxic oligosaccharide molecules (cyclodextrin, CD) were prepared and incorporated into biocompatible hydrogels for use as versatile sensors. The major component, carboxylated polypyrrole nanotubes (PPy(COOH) NTs) were fabricated using microemulsion polymerization and a critical sensing medium CD molecule was introduced via a simple surface engineering method. The resulting PPy (COOH)-CD NT hybrid complexes were incorporated into a hydrogel matrix for biocompatible applications. Consequently, a convenient sensor geometry was constructed by mounting the hydrogel on a gold micropattern for the detection of toxic substances. The feasibility of the produced sensor system was demonstrated, and the sensor performance was measured extensively using electrical measurements. It was found that the sensor could detect a model compound (methyl paraben, MPRB) at concentration as low as 1 nM. This study provides useful information for future research activities in relevant fields. (C) 2020 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
机译:在该研究中,制备由羧化聚吡咯(COOH))和无毒寡糖分子(环糊精,CD)组成的导电材料,并掺入生物相容性水凝胶中,用作多功能传感器。主要成分羧化聚吡咯纳米管(PPY(COOH)NTS)使用微乳液聚合制备,并通过简单的表面工程方法引入临界感测介质CD分子。将所得的PPY(COOH)-CD NT杂化复合物掺入水凝胶基质中,用于生物相容性应用。因此,通过将水凝胶安装在金微米图上以检测有毒物质来构造方便的传感器几何形状。证明了产生的传感器系统的可行性,并且使用电测量广泛测量传感器性能。发现传感器可以以低至1nm的浓度检测模型化合物(甲基羟基甲基,MPRB)。本研究为相关领域的未来研究活动提供了有用的信息。 (c)2020朝鲜工业与工程化学学会。 elsevier b.v出版。保留所有权利。

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