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首页> 外文期刊>Journal of industrial and engineering chemistry >Enhanced adhesion properties of conductive super-hydrophobic surfaces by using zirco-aluminate coupling agent
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Enhanced adhesion properties of conductive super-hydrophobic surfaces by using zirco-aluminate coupling agent

机译:通过使用Zirco-alumate偶联剂提高导电超疏水表面的粘附性能

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摘要

Various technical approaches and concepts have been proposed to develop conductive super hydrophobic (SH) surfaces. However, most of these approaches are not usable in practical applications because of insufficient adhesion and cost issues. Additionally, durability and uniformity issues are still in need of improvement. The goal of this research is to produce a large-area conductive SH surface with improved adhesion performance and uniformity. To this end, carbon nanotubes (CNT) with a high aspect ratio and elastomeric polymer were utilized as a conductive filler and matrix, respectively, to form a coating layer. Additionally, nanoscale silica particles were utilized for stable implementation of the conductive SH surface. To improve the adhesion properties between the SH coating layer and substrate, pretreatment of the substrate was conducted by utilizing both wet and dry etching processes to create specific organic functional groups on the substrate. Following pretreatment of the surface, a zircoaluminate coupling agent was utilized to enhance adhesion properties between the substrate and the SH coating layer. Raman spectroscopy revealed that adhesion was greatly improved by the formation of a chemical bond between the substrate and the SH coating layer at an optimal coupling agent concentration. The developed conductive SH coating attained a high electromagnetic interference (EMI) shielding effectiveness, which is advantageous in self-cleaning EMI shielding applications. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
机译:已经提出了各种技术方法和概念来开发导电超疏水性(SH)表面。然而,由于粘附性和成本问题不足,这些方法中的大部分方法都不可用。此外,耐用性和统一性问题仍然需要改进。该研究的目标是生产一种具有改善的粘合性能和均匀性的大面积导电SH表面。为此,分别使用具有高纵横比和弹性体聚合物的碳纳米管(CNT)作为导电填料和基质以形成涂层。另外,利用纳米级二氧化硅颗粒用于导电SH表面的稳定实施。为了改善SH涂层和基板之间的粘合性能,通过利用湿和干蚀刻工艺进行基板的预处理,以在基材上产生特定的有机官能团。在表面进行预处理后,利用锆拓偶联剂来增强基材和SH涂层之间的粘合性能。拉曼光谱表明,通过在最佳偶联剂浓度下形成基材和SH涂层之间的化学键来大大提高粘合力。开发的导电SH涂层达到了高电磁干扰(EMI)屏蔽效能,这在自清洁EMI屏蔽应用中是有利的。 (c)2018年韩国工程和工程化学学会。 elsevier b.v出版。保留所有权利。

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