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首页> 外文期刊>Journal of industrial and engineering chemistry >State-of-the-art modification of polymeric membranes by PEO and PEG for carbon dioxide separation: A review of the current status and future perspectives
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State-of-the-art modification of polymeric membranes by PEO and PEG for carbon dioxide separation: A review of the current status and future perspectives

机译:PEO和PEG用于二氧化碳分离的最先进的聚合物膜改性:对当前状态和未来观点的综述

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In this paper, the methods for modification of polymeric membranes with Poly (ethylene oxide) (PEO) and Poly (ethylene glycol) (PEG) for CO2 separation is reviewed. PEO-containing membranes considered due to their proper CO2 separation performances and simplicity in fabrication. However, high crystallization tendency and mechanical strength of these PEG-based membranes have limited their applications on commercial scale. Hence, various methods have been proposed to overcome these shortcomings and improve the performance of the membranes, such as blending with other polymers or the formation of new chemical structures by copolymerization and crosslinking. In this paper, the state-of-the-art for the polymeric membranes containing PEO or PEG for CO(2 )separation is investigated and the separation performance of each category is evaluated and finally, future research directions and recommendations in this field are proposed. According to the present study, in general, although the mixed matrix membranes have shown excellent performances for carbon dioxide separations, the ionic liquid containing membranes also have offered high permeability and selectivity than the other types of membranes, and it seems that the MMMs containing Its would be promising for future generation membranes. (C) 2019 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
机译:本文综述了用聚(环氧乙烷)(PEO)(PEO)和聚(乙二醇)和聚(乙二醇)(PEG)改性CO 2分离的方法。由于其适当的CO 2分离性能和制造中的简单性而认为含有含有的膜。然而,这些基于PEG的膜的高结晶趋势和机械强度限制了它们对商业规模的应用。因此,已经提出了各种方法来克服这些缺点并改善膜的性能,例如通过共聚合和交联与其他聚合物混合或形成新的化学结构。在本文中,研究了含有CO(2)分离的PEO或PEG的聚合物膜的最新膜,并评估每个类别的分离性能,最后,提出了该领域的未来研究方向和建议。根据本研究,通常,虽然混合基质膜具有优异的二氧化碳分离性能,但含离子液体的膜也具有比其他类型的膜更高的渗透性和选择性,并且似乎含有其的MMM对于未来的一代膜来说将是有希望的。 (c)2019年韩国工程化学学会。 elsevier b.v出版。保留所有权利。

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