Fabrication of high energy Li-ion hybrid capacitor using manganese hexacyanoferrate nanocubes and graphene electrodes

Pazhamalai Parthiban; Krishnamoorthy Karthikeyan; Mariappan Vimal Kumar; Kim Sang-Jae

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Fabrication of high energy Li-ion hybrid capacitor using manganese hexacyanoferrate nanocubes and graphene electrodes

机译：使用锰己酰基甲醛纳米尺和石墨烯电极的高能量锂离子混合电容器的制造

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Herein, we demonstrated a facile sonochemical preparation of manganese hexacyanoferrate (Mn-HCF) and examined its use as an intercalative-type electrode for Li-ion hybrid capacitors (LHCs). The X-ray diffraction, field-emission scanning electron microscopy, and X-ray photoelectron spectroscopic analyses revealed the formation of Mn-HCF nanocubes. The electrochemical analyses revealed the presence of ion-intercalation pseudocapacitance in the Mn-HCF electrode with a specific capacity of 81.59 mAh g(-1). In the view of practical applications, we designed a Mn-HCF parallel to graphene LHC which delivered a high specific capacitance (79.52 F g(-1)) and energy density (44.18 Wh kg(-1)), respectively. Overall, our results highlight the significance of Mn-HCF towards cost-effective energy storage devices. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

机译：在此，我们证明了锰己酰甲酸锰（MN-HCF）的容易的多种子化学制剂，并将其用作锂离子混合电容器（LHC）的嵌段型电极。 X射线衍射，场发射扫描电子显微镜和X射线光电子体光谱分析显示了Mn-HCF纳米尺寸的形成。电化学分析揭示了在Mn-HCF电极中的离子插入假偶像的存在，特定容量为81.59mAhg（-1）。在实际应用中，我们设计了与石墨烯LHC平行的MN-HCF，其分别输送了高比电容（79.52V（-1））和能量密度（44.18WHKG（-1））。总体而言，我们的结果突出了MN-HCF对具有成本效益的能量存储设备的重要性。（c）2018年韩国工程和工程化学学会。 elsevier b.v出版。保留所有权利。

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来源
《Journal of industrial and engineering chemistry》 |2018年第2018期|共9页
作者
Pazhamalai Parthiban; Krishnamoorthy Karthikeyan; Mariappan Vimal Kumar; Kim Sang-Jae;
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作者单位

Jeju Natl Univ Dept Mechatron Engn Jeju 63243 South Korea;

Jeju Natl Univ Dept Mechatron Engn Jeju 63243 South Korea;

Jeju Natl Univ Dept Mechatron Engn Jeju 63243 South Korea;

Jeju Natl Univ Dept Mechatron Engn Jeju 63243 South Korea;

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正文语种 eng
中图分类化学工业;
关键词
Li-ion hybrid capacitor; Manganese hexacyanoferrate; Graphene; Aqueous electrolyte; Energy density;

机译：锂离子混合电容;锰己酰基甲醛;石墨烯;水电解质;能量密度;

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1. Fabrication of high energy Li-ion hybrid capacitor using manganese hexacyanoferrate nanocubes and graphene electrodes [J] . Pazhamalai Parthiban, Krishnamoorthy Karthikeyan, Mariappan Vimal Kumar, Journal of industrial and engineering chemistry . 2018,第期

机译：使用锰己酰基甲醛纳米尺和石墨烯电极的高能量锂离子混合电容器的制造
2. High-energy aqueous Li-ion hybrid capacitor based on metal-organic-framework-mimicking insertion-type copper hexacyanoferrate and capacitive-type graphitic carbon electrodes [J] . Pazhamalai Parthiban, Krishnamoorthy Karthikeyan, Sahoo Surjit, Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2018,第期

机译：基于金属 - 有机框架模拟插入型铜六氰基甲醛和电容式石墨碳电极的高能锂离子混合电容器
3. Fabrication of manganese oxide@nitrogen doped graphene oxide/polypyrrole (MnO 2@NGO/PPy) hybrid composite electrodes for energy storage devices [J] . Sivalingam Ramesh, Hemraj M. Yadav, K. Karuppasamy, Journal of Materials Research and Technology . 2019,第5期

机译：储能器件中锰掺杂@氮掺杂氧化石墨烯/聚吡咯（MnO 2 @ NGO / PPy）混合复合电极的制备
4. The Influence of Manganese Ion Concentration in Preparation of Manganese Hexacyanoferrate Modified Electrode for Activated Glassy Carbon [C] . Xue Mingyue, Zhang Shengtao Marine Corrosion and Control . 2006

机译：锰离子浓度对锰酸高铁锰修饰玻碳活性电极制备的影响
5. Fabrication and Characterization of Li-Ion Electrodes for High-Power Energy Storage Devices [D] . Lai, Chun-Han. 2017

机译：高功率储能装置锂离子电极的制造与表征
6. Fabrication of high-performance dual carbon Li-ion hybrid capacitor: mass balancing approach to improve the energy-power density and cycle life [O] . Tandra Panja, Jon Ajuria, Noel Díez, -1

机译：高性能双碳锂离子混合电容器的制造：质量平衡方法可提高能量-功率密度和循环寿命
7. Fabrication of high-performance dual carbon Li-ion hybrid capacitor: mass balancing approach to improve the energy-power density and cycle life [O] . Tandra Panja, Jon Ajuria, Noel Díez, 2020

机译：高性能双碳锂离子混合电容的制作：质量平衡方法，提高能量 - 功率密度和循环寿命
8. Li-Ion, Ultra-capacitor Based Hybrid Energy Module [R] . Daboussi, Z., Paryani, A., Khalil, G., 2007

机译：基于锂离子电池的超级电容混合能量模块

Fabrication of high energy Li-ion hybrid capacitor using manganese hexacyanoferrate nanocubes and graphene electrodes

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