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首页> 外文期刊>Journal of Macromolecular Science. Pure and Applied Chemistry >Influence of processing temperature and pressure on the stability of the structure of hot-pressed ground leather: Pleather
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Influence of processing temperature and pressure on the stability of the structure of hot-pressed ground leather: Pleather

机译:加工温度和压力对热压地毯结构稳定性的影响:孔径

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摘要

The increased degree of transformation of leather to a material with thermoplastic properties is shown to increase this material's solubility in both dimethylsulfoxide and in a buffer similar to those used to dissolve high molecular weight proteins. This increase in solubility is controlled by the variable values of the processing parameters, temperature, and pressure, and is interpreted to suggest that this transformation of leather must be accompanied by the destruction of its collagen superstructure into-fragments with a much smaller molecular weight. This model is further supported by molecular weight distributions as determined by size exclusion chromatography and by electrophoresis. The results of the investigation at the molecular level are corroborated by scanning electron microscopy of pleather samples.
机译:显示出具有热塑性性质的材料的转化程度增加,以增加该材料在二甲基硫氧化物中的溶解度和类似于用于溶解高分子量蛋白的缓冲率。 溶解度的这种增加由加工参数,温度和压力的变量值控制,并被解释为表明皮革的这种转化必须伴随其胶原蛋白上层建筑物的破坏,具有更小的分子量。 通过尺寸排阻色谱和电泳确定的分子量分布进一步支持该模型。 通过扫描孔样品的电子显微镜,通过扫描电子显微镜来证实分子水平的研究结果。

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