首页> 外文期刊>Journal of Materials Chemistry, C. materials for optical and electronic devices >Tailored pyroresistive performance and flexibility by introducing a secondary thermoplastic elastomeric phase into graphene nanoplatelet (GNP) filled polymer composites for self-regulating heating devices
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Tailored pyroresistive performance and flexibility by introducing a secondary thermoplastic elastomeric phase into graphene nanoplatelet (GNP) filled polymer composites for self-regulating heating devices

机译:通过将二级热塑性弹性相相分割成石墨烯纳米薄板(GNP)填充的聚合物复合材料来定制达极性性能和灵活性,用于自调节加热装置

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Flexible and controllable self-regulating heating devices have great potential for use in applications such as healthcare devices, soft robotics, artificial skins and wearable electronics. Conventional self-regulating heating devices are often limited by the rigid nature of the polymer matrices, particularly at high conductive filler concentrations. In this paper, this limitation has been successfully tackled by using binary polymer blends that can achieve a desirable combination of mechanical, electrical and pyroresistive properties. The addition of a suitable secondary thermoplastic elastomeric polymeric phase did not only improve material flexibility, but did also tune the positive temperature coefficient (PTC) behaviour. For the first time, we systematically explore the effect of different blend morphologies as well as the selective localization of conductive fillers like graphene nanoplatelets (GNPs) on the overall mechanical and pyroresistive performance of self-regulating conductive polymer composites (CPCs). The effect of different blend morphologies was studied using different thermoplastic elastomers (TPEs) as secondary phases, and various blend compositions, into a GNP filled high density polyethylene (HDPE) nanocomposite. Blend morphologies included immiscible binary blends with a fine and coarse droplet morphology and a co-continuous morphology. In doing so, this study serves as a guideline for the selection of a secondary elastomeric phase in polymer blend based CPCs for optimised device flexibility and self-regulating heating functions.
机译:灵活可控的自调节加热装置具有很大的应用,适用于医疗器械,软机器人,人造皮肤和可穿戴电子产品等应用。传统的自调节加热装置通常受到聚合物基质的刚性性质的限制,特别是在高导电填料浓度下。在本文中,通过使用二元聚合物共混物成功地解决了该限制,该二进制聚合物共混物可以实现机械,电气和阈值性质的理想组合。加入合适的二级热塑性弹性体聚合物相不仅提高了材料柔韧性,而且还曲调了正温度系数(PTC)行为。我们首次系统地探讨了不同混合形态的效果以及像石墨烯纳米片(GNPS)这样的导电填料(GNP)的选择性定位对自调节导电聚合物复合材料(CPC)的整体机械和极致性能。使用不同的热塑性弹性体(TPE)作为二次相和各种共混物组合物研究不同共混形态的效果,进入GNP填充的高密度聚乙烯(HDPE)纳米复合材料。混合形态包括不混溶的二元混合物,具有细小的液滴形态和共同连续的形态。在这样做时,该研究用作在基于聚合物共混物的CPC中选择二次弹性体相的指导,用于优化的装置灵活性和自调节加热功能。

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