Tunable-emission and AIPE-active heteroleptic Ir(iii) complexes for fingermark detection via a spraying technique

Zhongming Song; Rui Liu; Xi Li; Hanbin Zhu; Yinghai Lu; Hongjun Zhu

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Tunable-emission and AIPE-active heteroleptic Ir(iii) complexes for fingermark detection via a spraying technique

机译：通过喷涂技术进行可调谐 - 发射和AIPE-活性异素IR（III）复合物用于指纹检测

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Latent fingermark detection has been a high profile issue in the field of identity authentication. In the present work, three cationic heteroleptic Ir( III ) complexes with the same ancillary ligand (N^N) and different cyclometalated ligands (C^N) were designed and synthesized. The complexes exhibited different solid-state emission colors and aggregation-induced phosphorescent emission (AIPE) properties, all of which could be tuned by modifying the substituent and conjugation groups. Additionally, owing to excellent AIPE and lipophilicity properties, these complexes were also used to detect partial and aged latent fingermarks on vertical surfaces and porous paper, obtaining clearly-defined third level details.

机译：潜在的FingerMark检测是身份认证领域的高调问题。在本作研究中，设计并合成了具有相同辅助配体（N ^ N）和不同环荷酸配体（C ^ N）的三种阳离子异常的IR（III）配合物。该配合物表现出不同的固态发光颜色和聚集致磷光发射（AIPE）性质，所有这些都可以通过改变取代基和缀合基团来调节。另外，由于AIPE和亲脂性性质优异，这些配合物还用于检测垂直表面和多孔纸上的部分和老化的潜在斑驳，获得明确限定的第三级细节。

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《Journal of Materials Chemistry, C. materials for optical and electronic devices》 |2018年第40期|共6页
作者
Zhongming Song; Rui Liu; Xi Li; Hanbin Zhu; Yinghai Lu; Hongjun Zhu;
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作者单位

School of Chemistry and Molecular Engineering Nanjing Tech University;

School of Chemistry and Molecular Engineering Nanjing Tech University;

School of Chemistry and Molecular Engineering Nanjing Tech University;

School of Chemistry and Molecular Engineering Nanjing Tech University;

School of Chemistry and Molecular Engineering Nanjing Tech University;

School of Chemistry and Molecular Engineering Nanjing Tech University;

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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
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1. Tunable-emission and AIPE-active heteroleptic Ir(iii) complexes for fingermark detection via a spraying technique [J] . Zhongming Song, Rui Liu, Xi Li, Journal of Materials Chemistry, C. materials for optical and electronic devices . 2018,第40期

机译：通过喷涂技术进行可调谐 - 发射和AIPE-活性异素IR（III）复合物用于指纹检测
2. Smart inks based on AIPE-active heteroleptic Ir(Ⅲ) complexes [J] . Song Zhongming, Liu Rui, Zhu Hanbin, Sensors and Actuators . 2019,第JANa期

机译：基于AIPE活性Ir（Ⅲ）配合物的智能油墨
3. DNA binding and anti-cancer activity of redox-active heteroleptic piano-stool Ru(II), Rh(III), and Ir(III) complexes containing 4-(2-methoxypyridyl)phenyldipyrromethene [J] . Gupta R.K., Pandey R., Sharma G., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2013,第7期

机译：含4-（2-甲氧基吡啶基）苯基二吡咯亚甲基的氧化还原活性杂多钢琴凳Ru（II），Rh（III）和Ir（III）配合物的DNA结合和抗癌活性
4. Heteroleptic cyclometalated Ir(III) complexes with charge transporting groups: a theoretical study [C] . Asanga B. Padmaperuma, Carlos A. Fernandez Organic light emitting materials and devices XVI. . 2012

机译：具有电荷传输基团的杂环金属Ir（III）配合物：理论研究
5. Novel applications of signal processing techniques in atomic spectrometry: I. Tomographic investigations of atomic reservoirs. II. Instrumentation for monitoring magnetically-induced polarization rotation in atomic vapors. III. An investigation of the noise characteristics of several atomic reservoirs. [D] . Monnig, Curtis Anthony. 1989

机译：信号处理技术在原子光谱中的新应用：I.原子储层的层析成像研究。二。监测原子蒸气中磁感应极化旋转的仪器。三，几个原子储层的噪声特性研究。
6. Synthesis Spectroscopy and Electrochemistry in Relation to DFT Computed Energies of Ferrocene- and Ruthenocene-Containing β-Diketonato Iridium(III) Heteroleptic Complexes. Structure of (2-Pyridylphenyl)2Ir(RcCOCHCOCH3 [O] . Blenerhassitt E. Buitendach, Jeanet Conradie, Frederick P. Malan, 2019

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Tunable-emission and AIPE-active heteroleptic Ir(iii) complexes for fingermark detection via a spraying technique

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