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Studying the Wettability and Reactivity of Liquid Si-Ti Eutectic Alloy on Glassy Carbon

机译:研究液体Si-Ti共晶合金对玻璃碳的润湿性和反应性

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The contact heating sessile drop method was applied for a fundamental study concerning the wettability and reactivity of liquid Si-16.2at.%Ti (eutectic composition) in contact with glassy carbon. The evolution of the contact angle behaviors and spreading kinetics were evaluated at three different temperatures. A strong temperature dependence was found by analyzing the spreading kinetics in determining the achievement of the equilibrium at the interface. Different spreading stages with different slopes depend on whether the diffusion of reacting phases (liquid Si and C) through the growing reaction layer (SiC) starts to be the rate-limiting factor. On the contrary, the final contact angle value seems not affected by the temperature. The solidified Si-Ti eutectics/GC samples were examined both at the top of the drop and at the cross section by SEM/EDS. The presence of C pockets of dissolution and a SiC layer at the interface confirmed the reactive nature of the interaction mechanisms. In addition, a thicker layer of SiC at the triple line was detected and most probably responsible for pinning the alloy drop at a measuredfinal value of contact angle of 43 degrees +/- 2.
机译:施用接触加热术式液滴法用于液体Si-16.2AT的润湿性和反应性的基本研究。%Ti(共晶组合物)与玻璃碳接触。在三种不同的温度下评估接触角行为和传播动力学的演变。通过分析展开动力学来确定在确定界面的平衡方面的实现来发现强烈的温度依赖性。具有不同斜率的不同扩散阶段取决于反应相(液体Si和C)的扩散是否通过生长反应层(SiC)开始是速率限制因子。相反,最终接触角值似乎不受温度的影响。通过SEM / EDS在下降顶部和横截面的顶部检查凝固的Si-Ti Eutectics / GC样品。在界面处的溶解和SiC层的存在证实了相互作用机制的反应性。另外,检测到三线的较厚的SiC层,并且最可能导致在43度+/- 2的接触角的测量极值处钉入合金下降。

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