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Effect of Surface Modification on Corrosion Resistance of Uncoated and DLC Coated Stainless Steel Surface

机译:表面改性对未涂覆和DLC涂层不锈钢表面耐腐蚀的影响

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摘要

Corrosion resistance of 4H13 stainless steel (EN-X46Cr13) surface uncoated and coated with an amorphous hydrogenated carbon (a-C:H) film [diamond-like carbon (DLC)] in acidic chloride solution was investigated. The DLC films were deposited on steel surface by a plasma deposition, direct current discharge (PDCD) method. The Fourier transform infrared (FTIR) was used to determine the chemical groups existing on DLC films. The surface of the specimens was observed by a scanning electron microscope (SEM). The tribological properties of the both materials were examined using a ball-on disk tribometer. The microhardness (HV) of diamond-like carbon film increased over five times in relation to the 4H13 stainless steel without of DLC coating. Oxidation kinetic parameters were determined by gravimetric and electrochemical methods. The high value of polarization resistance indicates that the DLC film on substrate was characterized by low electrical conductivity. The corrosion rate of 4H13 stainless steel with of DLC film decreased about eight times in relation to uncoated surface of 4H13 stainless steel.
机译:研究了4H13的耐腐蚀性(EN-X46CR13)表面未涂覆并涂有无定形氢化碳(A-C:H)膜[金刚石状碳(DLC)]在酸性氯化物溶液中。通过等离子体沉积,直流放电(PDCD)方法沉积DLC膜在钢结构上。傅里叶变换红外(FTIR)用于确定DLC膜上存在的化学基团。通过扫描电子显微镜(SEM)观察标本的表面。使用球盘摩擦计检查两种材料的摩擦学性质。金刚石状碳膜的显微硬度(HV)与没有DLC涂层的4H13不锈钢增加了五次。通过重量和电化学方法测定氧化动力学参数。偏振电阻的高值表明基板上的DLC膜的特征在于电导率低。与DLC膜的4H13不锈钢的腐蚀速率降低了4H13不锈钢的未涂覆表面的八次。

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