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Structural and Hydrogen Storage Properties of Mg60-Ni40 and Mg80-Ni20 Alloys Prepared by Planar Flow Casting

机译:由平面流量铸造制备的Mg60-Ni40和Mg80-Ni20合金的结构和储氢性能

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摘要

This study was carried out to better understand the chemical composition, microstructure, and hydrogen properties of Mg binary alloys. In this study, Mg60-Ni40 and Mg80-Ni20 (wt.%) alloy ribbons with different microstructures have been produced by the melt spinning method. The structural, hydriding, and dehydriding properties of the alloys were evaluated. The phase constitutions and microstructures were characterized by XRD and SEM studies. Microstructural grain sizes measured for Mg60-Ni40 alloy ribbons were in the range of 1-5 mu m, and the alloy contained finely dispersed Mg and Mg2Ni phases. In the case of Mg80-Ni20 alloy ribbons, the microstructural grain sizes were measured as less than 1 mu m. The hydrogen absorption and desorption capacities and kinetics of these two alloys were found to be highly dependent on microstructure and phase properties. Also, the amount of Ni content affected both the hydrogen storage capacities and kinetics for both of the Mg-Ni binary alloys. The increasing amount of Ni resulted in reduced hydrogen absorption capacity. The Mg60-Ni40 and Mg80-Ni20 alloy ribbons demonstrated superior hydrogenation absorption capacity at 350 degrees C and reversibly absorbed about 4.62 and 5.51 (wt.%) mass hydrogen, respectively.
机译:进行该研究以更好地了解Mg二元合金的化学成分,微观结构和氢性质。在该研究中,通过熔融纺丝方法制造了具有不同微观结构的Mg60-Ni40和Mg80-Ni20(wt.%)合金带。评价合金的结构,水合和脱水性质。通过XRD和SEM研究表征了相位构成和微观结构。测量Mg60-Ni40合金带测量的微结构粒度在1-5μm的范围内,合金含有精细分散的Mg和Mg2Ni相。在Mg80-Ni20合金带的情况下,测量微观结构粒度小于1μm。发现这两个合金的氢吸收和解吸能力和动力学高度依赖于微观结构和相质。此外,Ni含量的量影响了Mg-Ni二元合金两者的储氢容量和动力学。越来越多的Ni导致氢吸收能力降低。 Mg60-Ni40和Mg80-Ni20合金带分别在350℃下呈现出优异的氢化吸收能力,并分别可逆地吸收约4.62和5.51(wt。%)质量氢。

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