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Microstructure and Mechanical Properties of Nanostructured CoCrFeMoTi High-Entropy Alloy Fabricated by Mechanical Alloying and Spark Plasma Sintering

机译:机械合金化和火花等离子烧结制造的纳米结构COCRFEMOTI高熵合金的组织和力学性能

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摘要

CoCrFeMoTi high-entropy alloy (HEA) was synthesized using mechanical alloying and spark plasma sintering. The corresponding microstructural features and phase composition were compared with those of CoCrFeNi, CoCrFeNiTix (x = 0, 0.3 and 0.5) and CoCrFeNiMox (x = 0, 0.3, 0.5 and 0.85) HEAs. Co, Cr, Fe, Mo and Ti elemental powders were mixed in equiatomic ratio and mechanically alloyed in a planetary ball mill at 300 rpm for up to 80 h. The influence of the milling duration on the evolution of microstructure, constituent phases and morphology was studied. After 40 h of ball milling, two supersaturated BCC solid solution phases were obtained. Milling time increasing resulted in grain refinement and higher solid solution homogenization characterized by a high internal strain. A partial phase transformation from BCC to intermetallic phases when the temperature exceeds 660 degrees C was revealed. After SPS consolidation, the Vickers hardness was 778 +/- 10 HV, in combination with an ultimate shear stress of 216 +/- 20 MPa and a yield shear stress of 81 +/- 15 MPa for the material sintered at 950 degrees C and 65 MPa. Further increasing in the sintering temperature resulted in enhanced hardness value of 1600 +/- 5 but reduced yield shear stress. The failure analysis revealed a brittle fracture of the synthesized materials.
机译:COCRFEMOTI高熵合金(HEA)是使用机械合金化和火花等离子体烧结合成的。将相应的微观结构特征和相位组成与Cocrfeni,CoCrfenitix(x = 0,0.3和0.5)和CoCrfenimox(x = 0,0.3,0.5和0.85)进行比较。 CO,Cr,Fe,Mo和Ti元素粉末以赤脂比混合,并在行星球磨机中以300rpm机械合金合金,高达80小时。研究了研磨持续时间对微观结构,构成阶段和形态的演变的影响。在球磨40小时后,获得了两种过饱和的BCC固溶体相。铣削时间增加导致晶粒细化和较高的固体溶液均质化,其特征在于高内部菌株。揭示了当温度超过660摄氏度时从BCC到金属间相的部分相变。 SPS固结后,维氏硬度为778 +/- 10 HV,结合为216 +/-20MPa的最终剪切应力和81 +/- 15MPa的屈服剪应力,用于950摄氏度的材料烧结65 MPa。在烧结温度下进一步增加导致增强硬度值为1600 +/- 5但降低的产率剪切应力。失效分析显示了合成材料的脆性断裂。

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