Structure and Properties of Humic and Fulvic Acids. l. Properties and Reactivity of Humic Acids and Fulvic Acids

Martina Klucakova; Peter Pelikan; Lubomir Lapcik; Barbora Lapcikova; Jiri Kucerik; Michal Kalab

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Structure and Properties of Humic and Fulvic Acids. l. Properties and Reactivity of Humic Acids and Fulvic Acids

机译：腐殖质和富瑞酸的结构和性质。湖腐殖酸和富含酸的性质和反应性

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The aim of this part is to characterize of HA and FA on the basis of their ability to form complexes with inorganic and organic molecules capable to cause the effect of crosslinking. The characterization and properties of HA and FA and differences between these two groups of compounds were summarized. Their reactivity with transition elements was investigated by EPR spectroscopy. The properties of HA and FA in more details were studied by FTIR spectroscopy. With aid of semiempirical. version of INDO method parameterized for compounds of transition elements the interaction energies were calculated. Obtained results were discussed and compared.

机译：本部分的目的是在其形成具有能够引起交联效应的无机和有机分子的复合物的能力的基础上表征HA和Fa。总结了HA和FA的表征和性质以及这两组化合物之间的差异。通过EPR光谱研究了与转变元素的反应性。通过FTIR光谱研究了HA和FA的性质。借助半血统。用于转换元素化合物的Indo方法的版本计算了交互能量。获得并比较了得到的结果。

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来源
《Journal of Polymer Materials》 |2000年第4期|共20页
作者
Martina Klucakova; Peter Pelikan; Lubomir Lapcik; Barbora Lapcikova; Jiri Kucerik; Michal Kalab;
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作者单位

Institute of Physical and Applied Chemistry Faculty of Chemistry Technical University of Brno Purkynova 118 CZ-612 00 Brno Czech Republic;

Institute of Physical and Applied Chemistry Faculty of Chemistry Technical University of Brno Purkynova 118 CZ-612 00 Brno Czech Republic;

Department of Physics and Material Engineering Faculty of Technology Technical University of Brn nam T.G. Masaryka 275 Z-762 72 Zlin Czech Republic;

Department of Physics and Material Engineering Faculty of Technology Technical University of Brn nam T.G. Masaryka 275 Z-762 72 Zlin Czech Republic;

Institute of Physical and Applied Chemistry Faculty of Chemistry Technical University of Brno Purkynova 118 CZ-612 00 Brno Czech Republic;

Institute of Physical and Applied Chemistry Faculty of Chemistry Technical University of Brno Purkynova 118 CZ-612 00 Brno Czech Republic;

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正文语种 eng
中图分类高分子化合物工业（高聚物工业）;
关键词
Humic acid; fulvic acid; complex formation; transition element;

机译：腐殖酸;富含酸;复杂的形成;过渡元件;

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专利

1. Structure and Properties of Humic and Fulvic Acids. l. Properties and Reactivity of Humic Acids and Fulvic Acids [J] . Martina Klucakova, Peter Pelikan, Lubomir Lapcik, Journal of Polymer Materials . 2000,第4期

机译：腐殖质和富瑞酸的结构和性质。湖腐殖酸和富含酸的性质和反应性
2. III.Study of Complexation of Cu~(2+) Ions with Humic Acids in Sols:Study of Structure and Properties of Humic and Fulvic Acids. [J] . MARTINA KLUCAKOVA, MILOSLAV PEKAR Journal of Polymer Materials . 2003,第2期

机译：III。溶胶中Cu〜（2+）离子与腐殖酸的络合研究：腐殖酸和富勒酸的结构与性质研究。
3. Study of Structure and Properties of Humic and Fulvic Acids.IV.Study of Interactions of Cu~(2+) Ions with Humic Gels and Final Comparison [J] . MARTINA KLUCAKOVA, MILOSLAV PEKAR Journal of Polymer Materials . 2003,第2期

机译：腐殖酸和富勒酸的结构和性质研究IV.Cu〜（2+）离子与腐殖酸相互作用的研究及最终比较
4. Application of the coupled techniques in thermal analysis(thermogravimetrymass spectrometry-infrared spectroscopy)to study the structure and thermal properties of humic and fulvic acids [C] . P.BOGUTA, Z.SOKOLOWSKA, K.SKIC The Meeting of the International Humic Substances Society . 2019

机译：耦合技术在热分析中的应用（热重级法测定 - 红外光谱）研究腐殖质和富含酸的结构和热性能
5. Proton binding and aluminum complexation by soil humic and fulvic acids. [D] . Vance, George Floyd. 1990

机译：质子结合和铝被土壤腐殖酸和黄腐酸络合。
6. Use of thermal analysis coupled with differential scanning calorimetry, quadrupole mass spectrometry and infrared spectroscopy (TG-DSC-QMS-FTIR) to monitor chemical properties and thermal stability of fulvic and humic acids [O] . Patrycja Boguta, Zofia Sokołowska, Kamil Skic 2011

机译：将热分析与差示扫描量热法，四极质谱法和红外光谱法（TG-DSC-QMS-FTIR）结合使用，以监测黄腐酸和腐殖酸的化学性质和热稳定性
7. Use of thermal analysis coupled with differential scanning calorimetry, quadrupole mass spectrometry and infrared spectroscopy (TG-DSC-QMS-FTIR) to monitor chemical properties and thermal stability of fulvic and humic acids. [O] . Patrycja Boguta, Zofia Sokołowska, Kamil Skic 2017

机译：使用热分析结合差示扫描量热法，四极杆质谱和红外光谱（TG-DsC-Qms-FTIR）来监测黄腐酸和腐殖酸的化学性质和热稳定性。
8. Characterization of the International Humic Substances Society Standard and Reference Fulvic and Humic Acids by Solution State Carbon-13 (13C) and Hydrogen-1 (1H) Nuclear Magnetic Resonance Spectrometry [R] . Thorn, K. A., Folan, D. W., MacCarthy, P. 1989

机译：用溶液态碳-13（13C）和氢-1（1H）核磁共振光谱法表征国际腐殖物质学会标准和参考富里酸和腐殖酸

Structure and Properties of Humic and Fulvic Acids. l. Properties and Reactivity of Humic Acids and Fulvic Acids

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