An Intriguing Structural and Functional Analogy Between Large Cations and Anion-Centered (X2-Mn+) Clusters Exemplifiedby Double Chalcogenides K, Rb, Cs, TI(I) and Ag-(I), Cu-(I)

Bakakin V. V.

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An Intriguing Structural and Functional Analogy Between Large Cations and Anion-Centered (X2-Mn+) Clusters Exemplifiedby Double Chalcogenides K, Rb, Cs, TI(I) and Ag-(I), Cu-(I)

机译：大阳离子和阴离子（X2-Mn +）簇之间的有趣结构和功能性比例在双硫代胆碱基K，RB，Cs，Ti（I）和Ag-（I），Cu-（I）之间

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The structures of chalcogenides where some large S2-, Se2-, Te2- anions are closely surrounded by 6-12 Cu+ or Ag+ cations in 3-4 coordination are considered. These compact (X2-Mn+) groups, being the anion-centered clusters (ACCs), can be thought as highly charged voluminous analogues of large K, Rb, T1((I)), Cs cations. Together they perform related structural functions.

机译：考虑了一些大的S2-，SE2-，TE2-阴离子的硫属元素化物的结构被认为是3-4个协调中的6-12 Cu +或Ag +阳离子。这些紧凑型（X2-Mn +）基团是以阴离子为中心的簇（ACC），可以被认为是大K，RB，T1（（I）），CS阳离子的高度充电的体积相似之值。它们一起执行相关的结构功能。

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来源
《Journal of structural chemistry》 |2019年第3期|共8页
作者
Bakakin V. V.;
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作者单位

Russian Acad Sci Nikolaev Inst Inorgan Chem Siberian Branch Novosibirsk Russia;

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原文格式 PDF
正文语种 eng
中图分类结构化学;
关键词
chalcogenides; crystal structure; crystal chemical analysis; anion-centered clusters;

机译：硫属元素化物;晶体结构;晶体化学分析;以阴离子为中心的集群;

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1. An Intriguing Structural and Functional Analogy Between Large Cations and Anion-Centered (X2-Mn+) Clusters Exemplifiedby Double Chalcogenides K, Rb, Cs, TI(I) and Ag-(I), Cu-(I) [J] . Bakakin V. V. Journal of structural chemistry . 2019,第3期

机译：大阳离子和阴离子（X2-Mn +）簇之间的有趣结构和功能性比例在双硫代胆碱基K，RB，Cs，Ti（I）和Ag-（I），Cu-（I）之间
2. APPLICATION OF THE HYDRO(SOLVO)THERMAL TECHNIQUE TO THE SYNTHESIS OF METAL CARBONYL CHALCOGENIDE CLUSTERS .3. SYNTHESIS, STRUCTURAL CHARACTERIZATION, AND SPECTROSCOPIC STUDIES OF THE CLUSTERS [(M(CO)(4))(N)(MS(4))](2-) (M=MO, W N=1,2) [J] . Huang SP., Kanatzidis MG. Inorganica Chimica Acta . 1995,第1a2期

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An Intriguing Structural and Functional Analogy Between Large Cations and Anion-Centered (X2-Mn+) Clusters Exemplifiedby Double Chalcogenides K, Rb, Cs, TI(I) and Ag-(I), Cu-(I)

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