Structure and Properties of (C4N2H12)[Pt(NO3)(6)] Salt

Vasilehenko D. B.; Topchiyan P. A.; Tkachev S. V; Baidina I. A.; Korolkov I. V; Filatov E. Yu; Sheven D. G.

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Structure and Properties of (C4N2H12)[Pt(NO3)(6)] Salt

机译：（C4N2H12）[Pt（NO3）（6）]盐的结构和性质

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From a nitrate solution of platinum(IV) hydroxide, (C4N2H12)[Pt(N03)6] salt containing a piperazinium cation is isolated. The salt structure is determined by X-ray crystallography. Crystallographic data are: a=15.589(1)angstrom, b= 12.919(1) angstrom, c = 9.889(9)angstrom, beta = 08.625(4)degrees, space group C2/c, Z=4, rho(=)(calc) 2.306 g/cm(3). In the structure, [Pt(NO3)(6)](2-) anions having a shape of a trigonal antiprism are organized into a 3D network by the formation of hydrogen bonds with organic cations. For a series of salts containing [Pt(NO3)(6)](2-) and [Pt-2(omega-OH)(2)(NO3)(8)](2-) anionic platinum nitrato complexes a relationship between the structure and Pt-195 MAS NMR spectra is shown.

机译：从硝酸铂（IV）氢氧化物的硝酸盐溶液中，分离含有哌嗪阳离子的盐（C4N2H12）[Pt（NO 3）6]盐。盐结构由X射线晶体学确定。晶体数据是：A = 15.589（1）埃，B = 12.919（1）埃，C = 9.889（9）埃，β= 08.625（4）度，空间组C2 / C，Z = 4，Rho（=）（钙）2.306 g / cm（3）。在该结构中，通过形成具有有机阳离子的氢键组织成三角形抗抗抗逆转形状的[Pt（no3）（6）]（2-）阴离子。对于含有[Pt（NO 3）（6）]（2-）和[Pt-2（OMEGA-OH）（2）（2）（2）（8）]（2-）阴离子铂硝基络合物之间的关系示出了结构和PT-195MAS NMR光谱。

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来源
《Journal of structural chemistry》 |2019年第8期|共8页
作者
Vasilehenko D. B.; Topchiyan P. A.; Tkachev S. V; Baidina I. A.; Korolkov I. V; Filatov E. Yu; Sheven D. G.;
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Russian Acad Sci Nikolaev Inst Inorgan Chem Siberian Branch Novosibirsk Russia;

Russian Acad Sci Nikolaev Inst Inorgan Chem Siberian Branch Novosibirsk Russia;

Russian Acad Sci Nikolaev Inst Inorgan Chem Siberian Branch Novosibirsk Russia;

Russian Acad Sci Nikolaev Inst Inorgan Chem Siberian Branch Novosibirsk Russia;

Russian Acad Sci Nikolaev Inst Inorgan Chem Siberian Branch Novosibirsk Russia;

Russian Acad Sci Nikolaev Inst Inorgan Chem Siberian Branch Novosibirsk Russia;

Russian Acad Sci Nikolaev Inst Inorgan Chem Siberian Branch Novosibirsk Russia;

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正文语种 eng
中图分类结构化学;
关键词
platinum; nitrato complexes; piperazine; X-ray crystallographic analysis; MAS NMR;

机译：铂;硝酸盐复合物;哌嗪;X射线晶体分析;MAS NMR;

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1. Structure and Properties of (C4N2H12)[Pt(NO3)(6)] Salt [J] . Vasilehenko D. B., Topchiyan P. A., Tkachev S. V, Journal of structural chemistry . 2019,第8期

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Structure and Properties of (C4N2H12)[Pt(NO3)(6)] Salt

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