X-ray photoelectron and voltammetry studies of the charged state of the metal atom in nickel(II) chelate complexes with ligands containing CS2- and PS2- groups and in their mixed-ligand complexes

Mazalov LN; Trubina SV; Glezneva IM; Kryuchkova NA; Tarasenko OV; Varand VL; Kokina TE; Larionov SV

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X-ray photoelectron and voltammetry studies of the charged state of the metal atom in nickel(II) chelate complexes with ligands containing CS2- and PS2- groups and in their mixed-ligand complexes

机译：X射线光电子和伏安 - 镍（II）螯合络合物中金属原子的带电状态的伏安，含有Cs2和Ps2-基团的配体和混合配体复合物

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X-ray photoelectron and voltammetry studies of the charged state of the metal atom in nickel(II) chelate complexes with ligands containing CS2- and PS2- groups and in heteroligand complexes on their basis were carried out. It is shown that the degree of formal oxidation of the nickel atom in the complexes corresponds to Ni(II). In the case of heteroligand complexes, addition of nitrogen heterocycles causes an increase in the electron density on the atoms of the coordination center. Theoretical data obtained in ab initio quantum chemical model calculations correlate with the experimental results.

机译：进行X射线光电子和镍（II）螯合络合物的金属原子的带电状态的研究，其基于含有Cs2-和Ps2-基团的配体和杂种配合物的螯合配合物。结果表明，复合物中镍原子的正式氧化程度对应于Ni（II）。在杂酚配合物的情况下，加入氮杂环导致协调中心原子上的电子密度增加。在AB Initio量子化学模型计算中获得的理论数据与实验结果相关。

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来源
《Journal of structural chemistry》 |2005年第3期|共4页
作者
Mazalov LN; Trubina SV; Glezneva IM; Kryuchkova NA; Tarasenko OV; Varand VL; Kokina TE; Larionov SV;
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作者单位

Russian Acad Sci AV Nikolaev Inst Inorgan Chem Siberian Div Novosibirsk Russia;

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原文格式 PDF
正文语种 eng
中图分类结构化学;
关键词
chelate complexes of Ni(II); X-ray photoelectron spectroscopy; voltammetry investigations; ab initio quantum chemical calculations; SINGLE-SOURCE PRECURSORS;

机译：Ni（II）的螯合物复合物;X射线光电子体光谱;伏安调查;AB Initio量子化学计算;单源前体;

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1. X-ray photoelectron and voltammetry studies of the charged state of the metal atom in nickel(II) chelate complexes with ligands containing CS2- and PS2- groups and in their mixed-ligand complexes [J] . Mazalov LN, Trubina SV, Glezneva IM, Journal of structural chemistry . 2005,第3期

机译：X射线光电子和伏安 - 镍（II）螯合络合物中金属原子的带电状态的伏安，含有Cs2和Ps2-基团的配体和混合配体复合物
2. Metal Thiocyanato Complexes: Synthesis, Magnetic, and Spectral Studies of Some Mixed-Ligand Thiocyanato Complexes of Nickel(II) Involving Benzothiazole and Benzimidazole Derivatives [J] . R. C. Maurya, P. Sharma, D. Sutradhar Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry . 2003,第3期

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机译：混合配体复合物的研究。 III。含有二价金属的阿仑杀和甘氨酸之间的混合配体复合物

X-ray photoelectron and voltammetry studies of the charged state of the metal atom in nickel(II) chelate complexes with ligands containing CS2- and PS2- groups and in their mixed-ligand complexes

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