Synthesis, Characterization, and Crystal Structure Analysis of New Mixed Metal Sulfate NaPr(SO4)(2)(H2O)

Paul A. K.; Kanagaraj R.

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Synthesis, Characterization, and Crystal Structure Analysis of New Mixed Metal Sulfate NaPr(SO4)(2)(H2O)

机译：新混合金属硫酸盐NaPR（SO4）（2）（H2O）的合成，表征和晶体结构分析

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A crystalline mixed-metal sulfate compound NaPr(SO4)(2)(H2O) is synthesized under hydrothermal conditions and thoroughly characterized. Sodium bisulfite (NaHSO3) and piperazine are used with praseodymium acetate to obtain this sulfate-based structure. The single crystal structural analysis shows that the compound has the NaCe(SO4)(2) H2O structure type and crystallizes in the trigonal space group P3(2)21 (No. 154) with a = 6.9872(2) , c = 12.8935(8) , and V = 545.14(4) (3). The compound has three-dimensional connectivity formed by the sulfate units with Pr and Na centers. Tricapped trigonal prismatic PrO9 units and square-antiprismatic NaO8 units link to the SO4 tetrahedron for building the three-dimensional structure. The compound is also characterized by PXRD, TGA, and FT-IR spectroscopy. The present study illustrates the usefulness of the bisulfite anion and secondary amine for the chiral structure building.

机译：结晶混合金属硫酸盐化合物NaPR（SO 4）（2）（2）（H 2 O）在水热条件下合成，并彻底表征。亚硫酸氢钠（NaHSO3）和哌嗪与丙酸镨一起使用，得到这种基于硫酸盐的结构。单晶结构分析表明，该化合物具有NACE（SO4）（2）H2O结构型，并在三角空间组P3（2）21（No.154）中结晶，具有A = 6.9872（2），C = 12.8935（ 8），v = 545.14（4）（3）。该化合物具有由硫酸盐单元形成的三维连接，具有PR和Na中心。截断的三角形棱镜PRO9单位和方抗转NAO8单元连接到SO4四面体以构建三维结构。该化合物的特征还在于PXRD，TGA和FT-IR光谱。本研究说明了亚硫酸氢盐阴离子和仲胺用于手性结构建筑的有用性。

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来源
《Journal of structural chemistry》 |2019年第3期|共8页
作者
Paul A. K.; Kanagaraj R.;
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作者单位

Natl Inst Technol Kurukshetra Kurukshetra Haryana India;

Natl Inst Technol Kurukshetra Kurukshetra Haryana India;

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原文格式 PDF
正文语种 eng
中图分类结构化学;
关键词
mixed metal; praseodymium sulfate; single crystal; FT-IR; TGA;

机译：混合金属;硫酸镨;单晶;FT-IR;TGA;

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1. Synthesis, Characterization, and Crystal Structure Analysis of New Mixed Metal Sulfate NaPr(SO4)(2)(H2O) [J] . Paul A. K., Kanagaraj R. Journal of structural chemistry . 2019,第3期

机译：新混合金属硫酸盐NaPR（SO4）（2）（H2O）的合成，表征和晶体结构分析
2. Syntheses and crystal structures of hydrated ternary cerium sulfates: Mixed-valence K5Ce2(SO4)(6)center dot H2O and K2Ce(SO4)(3)center dot H2O [J] . Casari BM, Langer V Zeitschrift fur Anorganische und Allgemeine Chemie . 2007,第7期

机译：水合三价硫酸铈的合成和晶体结构：混合价K5Ce2（SO4）（6）中心点H2O和K2Ce（SO4）（3）中心点H2O
3. Synthesis, crystal structures, phase transition characterization and thermal decomposition of a new dabcodiium hexaaquairon(II) bis(sulfate): (C6H14N2)[Fe(H2O)(6)](SO4)(2) [J] . Yahyaoui S, Rekik W, Naili H, International Journal of Quantum Chemistry . 2007,第12期

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4. A Novel Hybrid Compound Based on Polyoxometalate, Synthesis and Crystal Structure ofSm(NMP)4(H2O)4 HSiMo12O40·2NMP·H2O [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

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5. New phases in the hydrous ferric sulfate system, a supporting argument that the mineral lausenite is of formula Fe2(SO4 )3·5H2O and the crystal structure refinement and hydrogen bonding scheme of the minerals quenstedtite and romerite [D] . Westland, Robin Elizabeth 2012

机译：含水硫酸铁体系中的新相，支持的论据是，矿物绿铁矿的分子式为Fe2（SO4）3·5H2O，以及芒硝和硅镁矿矿物的晶体结构细化和氢键合方案
6. Synthesis and crystal structure of a new polymorph of potassium europium(III) bis(sulfate) monohydrate KEu(SO4)2·H2O [O] . Avijit Kumar Paul 2018

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7. Crystal Chemistry and Structural Complexity of Uranium(IV) Sulfates: Synthesis of U3H2(SO4)7(H2O)53H2O and U3(UO2)0.2(SO4)6(OH)0.42.3H2O with Framework Structures by the Photochemical Reduction of Uranyl [O] . -1

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Synthesis, Characterization, and Crystal Structure Analysis of New Mixed Metal Sulfate NaPr(SO4)(2)(H2O)

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