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首页> 外文期刊>Journal of Vinyl & Additive Technology >The surface modification of BaTiO3 and its effects on the microstructure and electrical properties of BaTiO3/silicone rubber composites
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The surface modification of BaTiO3 and its effects on the microstructure and electrical properties of BaTiO3/silicone rubber composites

机译:BATIO3的表面改性及其对BATIO3 /硅橡胶复合材料微观结构和电性能的影响

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摘要

Interfacial interaction and compatibility between the ceramic dielectric and polymer matrix have strong impact on the dielectric constant and dielectric loss of their composites. In this work, the BaTiO3 (BT) nanoparticles were modified by (1) stearic acid (SA); (2) aluminate coupling agent (ACA); (3) the combination of SA and coupling agent aluminate, and then incorporated them with silicone rubber (SR) matrix to prepare BT/SR nanocomposites. The effects of the surface modification methods of BT on the microstructure and electrical properties of BT/SR nanocomposite films were studied. The results showed that SA and ACA were beneficial to the dispersion of BT and resulted in the strong interfacial interaction. The composite of BT modified by SA not only had high dielectric constant of 10.5, 2 times higher than that of the unmodified BT/SR nanocomposite (4.7), at the same time showed lower dielectric loss. J. VINYL ADDIT. TECHNOL., 24:288-294, 2018. (c) 2017 Society of Plastics Engineers
机译:陶瓷电介质和聚合物基质之间的界面相互作用和相容性对它们复合材料的介电常数和介电损失具有很强的影响。在这项工作中,BATIO3(BT)纳米颗粒被(1)硬脂酸(SA)改性; (2)铝酸盐偶联剂(ACA); (3)SA和偶联剂铝酸盐的组合,然后用硅橡胶(SR)基质掺入它们以制备BT / SR纳米复合材料。研究了BT的表面改性方法对BT / SR纳米复合膜微观结构和电性能的影响。结果表明,SA和ACA对BT的分散有益,导致强烈的界面相互作用。通过SA改性的BT的复合材料不仅具有10.5的高介电常数,而不是未经修改的BT / SR纳米复合材料(4.7)的高介电常数(4.7),同时显示出较低的介电损耗。 J.乙烯基添加剂。 Technol。,24:288-294,2018。(c)2017年塑料工程师协会

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    Qingdao Univ Sci &

    Technol Coll Polymer Sci &

    Engn Shandong Prov Key Lab Rubber Plast Minist Educ Key Lab Rubber Plast Qingdao 266042 Peoples R China;

    Qingdao Univ Sci &

    Technol Coll Polymer Sci &

    Engn Shandong Prov Key Lab Rubber Plast Minist Educ Key Lab Rubber Plast Qingdao 266042 Peoples R China;

    Qingdao Univ Sci &

    Technol Coll Polymer Sci &

    Engn Shandong Prov Key Lab Rubber Plast Minist Educ Key Lab Rubber Plast Qingdao 266042 Peoples R China;

    Qingdao Univ Sci &

    Technol Coll Polymer Sci &

    Engn Shandong Prov Key Lab Rubber Plast Minist Educ Key Lab Rubber Plast Qingdao 266042 Peoples R China;

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  • 正文语种 eng
  • 中图分类 高分子化合物工业(高聚物工业);
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