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Preparation and thermal property of ultrahigh molecular weight polyethylene composites filled by calcium carbonate modified with long chain

机译:长链碳酸钙填充超高分子量聚乙烯复合材料的制备及热性能

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摘要

Ultrahigh molecular weight polyethylene (UHMWPE) is an excellent property polymer, but its poor processability due to high melt viscosity limits the more wide-ranging application. To improve the processability of UHMWPE composites filled by calcium carbonate (CaCO3), a novel method is reported to modify CaCO3. PE wax coated on the surface of CaCO3 (PEW@CaCO3) can be prepared by acrylic acid-modified CaCO3 (AA-CaCO3) and PE wax. The crystallization and melting behavior of UHMWPE and its composites filled by CaCO3, AA-CaCO3, and PEW@CaCO3 was compared by differential scanning calorimetry. The processability of UHMWPE composites was characterized by torque rheometer. The effect of CaCO3, AA-CaCO3, and PEW@CaCO3 on the crystallization and processability of UHMWPE was discussed.
机译:超高分子量聚乙烯(UHMWPE)是优异的性质聚合物,但由于高熔体粘度限制了较高的应用,其可加工性差。 为了改善碳酸钙填充的UHMWPE复合材料的可加工性(CaCO 3),据报道了一种新方法来修饰CaCO 3。 涂覆在CaCO 3表面(PEW @ Caco3)上的PE蜡可以通过丙烯酸改性的CaCO 3(AA-CaCO 3)和PE蜡来制备。 通过差分扫描量热法比较UHMWPE的结晶和熔融行为及其通过CaCO3,AA-CaCO 3和PEW @ Caco3的复合物。 通过扭矩流变仪的特征是UHMWPE复合材料的可加工性。 讨论了CaCO3,AA-CaCO3和PEW @ CaCO3对UHMWPE结晶和加工性的影响。

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  • 作者单位

    Sun Yat Sen Univ Guangdong Prov Key Lab High Performance Polymer B Key Lab Polymer Composites &

    Funct Mat Mat Sci Inst Sch Chem Minist Educ Guangzhou 510275 Peoples R China;

    Sun Yat Sen Univ Guangdong Prov Key Lab High Performance Polymer B Key Lab Polymer Composites &

    Funct Mat Mat Sci Inst Sch Chem Minist Educ Guangzhou 510275 Peoples R China;

    Sun Yat Sen Univ Guangdong Prov Key Lab High Performance Polymer B Key Lab Polymer Composites &

    Funct Mat Mat Sci Inst Sch Chem Minist Educ Guangzhou 510275 Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 合成树脂及塑料;工程材料学;
  • 关键词

    UHMWPE; modified calcium carbonate; torque; XRD; DSC;

    机译:UHMWPE;改性碳酸钙;扭矩;XRD;DSC;

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