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Two-phase partitioning bioreactors for treatment of volatile organic compounds

机译:两相分配生物反应器,用于处理挥发性有机化合物

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摘要

Two-phase partitioning bioreactors (TPPBs) allow the biological removal of volatile organic compounds (VOCs) from contaminated gas streams at unprecedented rates and concentrations. TPPBs are constructed by adding a non-aqueous phase (e.g. hexadecane, silicone oil) to an aqueous phase that contains the microorganisms responsible for degrading the VOCs. Presence of a water-immiscible phase improves the transfer of hydrophobic substrates (e.g. hexane, oxygen) or reduces the toxicity of inhibitory substances (e.g. benzene, toluene) to the microorganisms present in the aqueous phase. The non-aqueous phase is selected based on cost, safety, good partitioning properties towards the target pollutants, biocompatibility, and non-biodegradability. TPPBs have hitherto been designed as laboratory-scale well-mixed stirred-tank reactors or as biofilters that contain a non-aqueous phase. Scale-up and industrial use of TPPBs require elucidation and modeling of the mechanisms of substrate transfer and uptake; understanding of the mechanisms of microbial selection; identification or synthesis of new inexpensive and robust non-aqueous phases; and generation of suitable guidelines for process design and control.
机译:两相分配生物反应器(TPPB)可以以前所未有的速率和浓度从污染的气流中生物去除挥发性有机化合物(VOC)。 TPPB是通过将非水相(例如十六烷,硅油)添加到含有负责降解VOC的微生物的水相中而构建的。与水不混溶的相的存在改善了疏水性底物(例如己烷,氧)的转移或降低了抑制性物质(例如苯,甲苯)对水相中存在的微生物的毒性。基于成本,安全性,对目标污染物的良好分配特性,生物相容性和非生物降解性来选择非水相。迄今为止,TPPB已被设计为实验室规模的充分混合的搅拌釜反应器或包含非水相的生物滤池。 TPPB的大规模生产和工业用途需要阐明和建模底物转移和吸收的机制;了解微生物选择的机制;鉴定或合成新的廉价而坚固的非水相;并为过程设计和控制生成合适的指南。

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