Fabrication of a Cu2ZnSn(S,Se)4 Photovoltaic Device by a Low-Toxicity Ethanol Solution Process

Gang Wang; Wangen Zhao; Yong Cui

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Fabrication of a Cu2ZnSn(S,Se)4 Photovoltaic Device by a Low-Toxicity Ethanol Solution Process

机译：低毒性乙醇溶液法制备Cu2ZnSn（S，Se）4光伏器件

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Homogeneous molecular precursor solutions are excellent choices for obtaining smooth absorber layers, and they offer the potential to significantly lower the manufacturing cost of solar cells. Here, we present a thermally degradable metal butyldithiocarbamate-based solution approach to fabricate Cu2ZnSn(S,Se)4 solar cells. Low-cost Cu2O, ZnO, and SnO were used as the starting materials and were dissolved in the ethanol solution of butyldfthiocarbamic acid. By tuning the composition of the Cu2ZnSn(S,Se)4 thin film, a power conversion efficiency of 6.03% on the basis of the active area has been achieved.

机译：均质的分子前驱体溶液是获得光滑吸收层的绝佳选择，它们具有显着降低太阳能电池制造成本的潜力。在这里，我们提出了一种可热降解的金属丁基二硫代氨基甲酸酯基溶液解决方案来制造Cu2ZnSn（S，Se）4太阳能电池。低成本的Cu2O，ZnO和SnO用作原料，并溶解在丁基二硫代氨基甲酸的乙醇溶液中。通过调节Cu 2 ZnSn（S，Se）4薄膜的组成，基于有源区域实现了6.03％的功率转换效率。

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《ACS applied materials & interfaces》 |2013年第20期|共6页
作者
Gang Wang; Wangen Zhao; Yong Cui;
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正文语种 eng
中图分类化学工业;
关键词
CZTSSe; kesterite; thin film; solar cells; solution process;

机译：CZTSSe;钾长石;薄膜;太阳能电池;固溶过程;

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1. Fabrication of a Cu2ZnSn(S,Se)4 Photovoltaic Device by a Low-Toxicity Ethanol Solution Process [J] . Gang Wang, Wangen Zhao, Yong Cui ACS applied materials & interfaces . 2013,第20期

机译：低毒性乙醇溶液法制备Cu2ZnSn（S，Se）4光伏器件
2. Fabrication of Cu2ZnSn(S,Se)(4) photovoltaic devices with 10% efficiency by optimizing the annealing temperature of precursor films [J] . Zhang Pengpeng, Yu Qing, Min Xue, RSC Advances . 2018,第8期

机译：通过优化前体膜的退火温度，用10％效率制造Cu2Znsn（SE）（4）光伏器件的制造
3. Improving the Performance of Solution-Processed Cu2ZnSn(S,Se)(4) Photovoltaic Materials by Cd2+ Substitution [J] . Fu Jie, Tian Qingwen, Zhou Zhengji, Chemistry of Materials: A Publication of the American Chemistry Society . 2016,第16期

机译：通过Cd2 +替代提高固溶处理的Cu2ZnSn（S，Se）（4）光伏材料的性能
4. Cu2ZnSn(S, Se)4 thin-film photovoltaic devices using non-vacuum based processing [C] . Meijun Lu Photovoltaic Specialists Conference (PVSC), 2011 37th IEEE . 2011

机译：使用基于非真空的工艺的Cu2ZnSn（S，Se）4薄膜光伏器件
5. Cu2ZnSn(S,Se)4 photovoltaic absorber fabrication by hydride chalcogenization of electrodeposited precursors. [D] . Mangan, Thomas Christopher. 2015

机译：通过对电沉积前体进行氢化硫属元素化制备Cu2ZnSn（S，Se）4光伏吸收体。
6. Fabrication of Fully Solution Processed Inorganic Nanocrystal Photovoltaic Devices [O] . Troy K. Townsend, Dario Durastanti, William B. Heuer, 2016

机译：完全溶液处理的无机纳米晶体光伏器件的制备
7. Fabrication of Cu2ZnSn(S,Se)4photovoltaic devices with 10 efficiency by optimizing the annealing temperature of precursor films [O] . Pengpeng Zhang, Qing Yu, Xue Min, 2018

机译：通过优化前体薄膜的退火温度，具有10％效率的Cu2zNSN（SE，SE）4伏的制造

Fabrication of a Cu2ZnSn(S,Se)4 Photovoltaic Device by a Low-Toxicity Ethanol Solution Process

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