A Career in Catalysis: John E. Bercaw

Wolczanski Peter T.; Chirik Paul J.

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A Career in Catalysis: John E. Bercaw

机译：催化职业：约翰·E·伯考（John E. Bercaw）

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On the occasion of Professor John Bercaw's 70th birthday, we reflect and highlight his distinguished career in organometallic chemistry and homogeneous catalysis. What began as a fundamental interest in the chemistry of bis(cyclopentadienyl)titanium compounds and their interaction with molecular nitrogen evolved into a vibrant and diverse program tackling some of the most important problems in catalysis. Using well-defined organometallic Compounds, fundamental insights were gained in the mechanism of CO reduction; basic transformations of organometallic-chemistry, such as alkene insertion and alkyl beta-hydrogen elimination; the origin of stereocontrol in rrietallocene-catalyzed polymerization; and in the activation of hydrocarbons by electrophilic late transition metals.

机译：在约翰·伯考（John Bercaw）教授诞辰70周年之际，我们反思并强调他在有机金属化学和均相催化领域的杰出职业。对双（环戊二烯基）钛化合物的化学及其与分子氮的相互作用的基本兴趣开始演变为一个充满活力且多样化的程序，解决了催化中一些最重要的问题。使用定义明确的有机金属化合物，在减少CO的机理方面获得了基本见识。有机金属化学的基本转变，例如烯烃插入和烷基β-氢消除;立体异构体催化的立体聚合反应的起源;以及通过亲电子的后期过渡金属活化碳氢化合物。

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《ACS catalysis》 |2015年第3期|共11页
作者
Wolczanski Peter T.; Chirik Paul J.;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
CO reduction; metallocene; polymerization; C-H activation;

机译：一氧化碳还原;茂金属;聚合;C-H活化;

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A Career in Catalysis: John E. Bercaw

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