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首页> 外文期刊>ACS Macro Letters >Jamming of Knots along a Tensioned Chain
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Jamming of Knots along a Tensioned Chain

机译:沿着张紧的链条打结

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摘要

We examine the motion of a knot along a tensioned chain whose backbone is corrugated due to excluded volume effects. At low applied tensions, the knot traverses the chain diffusively, while at higher tensions the knot makes slow, discrete hops that can be described as a Poisson process. In this "jammed" regime, the knot's long-time diffusivity decreases exponentially with increasing tension. We quantify how these measurements are altered by chain rigidity and the corrugation of the polymer backbone. We also characterize the energy barrier of the reptation moves that gives rise to the knot's motion. For the simple knot types examined thus far (3(1), 4(1), 5(1), 5(2)), the dominant contribution to the energy landscape appears in the first step of reptation-i.e., polymer entering the knotted core. We hope this study gives insight into what physics contributes to the internal friction of highly jammed knots.
机译:我们检查了沿张紧链的结的运动,该张紧的主链由于排除了体积影响而呈波纹状。在较低的施加张力下,结会扩散地穿过链条,而在较高的张力下,结会产生缓慢的离散跃点,可以说是泊松过程。在这种“阻塞”状态下,结的长期扩散率随着张力的增加呈指数下降。我们量化这些测量如何通过链刚性和聚合物主链的波纹来改变。我们还描述了引起结的运动的后移运动的能量屏障。对于到目前为止研究的简单结类型(3(1),4(1),5(1),5(2)),对能量态势的主要贡献出现在展开的第一步,即聚合物进入打结的核心。我们希望这项研究能深入了解物理因素如何导致高度阻塞的结的内部摩擦。

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