Current Trends in the Development of Investigations into the Microheterogeneous Mechanism of Three-Dimensional Radical Polymerization

G.V.Korolev

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Current Trends in the Development of Investigations into the Microheterogeneous Mechanism of Three-Dimensional Radical Polymerization

机译：当前趋势调查发展成三维自由基聚合的微观非均相机制

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Data on the kinetics and mechanism of three-dimensional radical polymerisation of polyfunctional vinyl monomers(oligomers)containing two(or more)double bonds are generalized.The history of this problem is outlined,a characteristic feature of its mechanism,i.e.,microheterogeneity,is considered.The attention is focused on a new phase in the development of investigations,namely,of three-dimensional polymerisation(the last decade),which is related to the advent of new techniques(fiber-optic techniquen information technology,etc.).Methodological features of kinetics experiments in highly structured reaction media in which three-dimensional radical polymerisation takes place,are discussed.

机译：含有两个（或更多）双键的多官能乙烯基单体（低聚物）的三维自由基聚合的动力学和机理的数据是概括的。概述了该问题的历史，其机制的特征，即微观的能力，是考虑到。目前的注意力集中在调查的发展中的新阶段，即三维聚合（过去十年）的开发，这与新技术的出现有关（光纤技术信息技术等）。讨论了高度结构化反应介质中动力学实验的方法论特征，其中进行了三维自由基聚合的方法。

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《Успехи химии》 |2003年第3期|共23页
作者
G.V.Korolev;
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Institute of Problems of Chemical Physics Russian Academy of Sciences 142432 Chernogolovka Moscow Region Russian Federation;

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正文语种 rus
中图分类化学;
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1. Current Trends in the Development of Investigations into the Microheterogeneous Mechanism of Three-Dimensional Radical Polymerization [J] . G.V.Korolev Успехи химии . 2003,第3期

机译：当前趋势调查发展成三维自由基聚合的微观非均相机制
2. Current trends in investigations into the microheterogeneous mechanism of three-dimensional raidcal polymerisation [J] . G V Korolev Russian Chemical Reviews: Reviews on Current Topics in Chemistry . 2003,第3期

机译：三维Raidcal聚合反应的微观非均质机理研究的最新趋势
3. Kinetics and reaction mechanism of template polymerization investigated by conductimetric measurements Part 4. Radical polymerization of acrylic acid in the presence of poly(vinyl alcohol):characterization of resulting polymer blends [J] . Gianluca Ciardelli, Niccoletta Barbani, Iacopo Rainaldi, Polymer international . 2001,第5期

机译：用电导测量法研究模板聚合的动力学和反应机理第4部分。在聚乙烯醇存在下丙烯酸的自由基聚合：所得聚合物共混物的表征
4. Polymer Biocatalysis and Biomaterials: Current Trends and Developments [C] . Symposium on polymer biocatalysis and biomaterials II . 2008

机译：聚合物生物催化和生物材料：当前的趋势和发展
5. Mechanistic and theoretical studies in cation radical chemistry: The cation radical mechanism of polymerization, polar vs. cation radical mechanisms, and inner sphere vs. outer space electron transfer. [D] . Aplin, Jeffrey Todd. 1997

机译：阳离子自由基化学的机理和理论研究：聚合的阳离子自由基机理，极性与阳离子自由基机理以及内球与外层空间电子转移。
6. Green Polymer Chemistry: Investigating the Mechanism of Radical Ring-Opening Redox Polymerization (R3P) of 36-Dioxa-18-octanedithiol (DODT) [O] . Emily Q. Rosenthal-Kim, Judit E. Puskas 2015

机译：绿色高分子化学：研究36-Dioxa-18-octanedithiol（DODT）的自由基开环氧化还原聚合（R3P）的机理
7. Green Polymer Chemistry: Investigating the Mechanism of Radical Ring-Opening Redox Polymerization (R3P) of 3,6-Dioxa-1,8-octanedithiol (DODT) [O] . Emily Q. Rosenthal-Kim, Judit E. Puskas 2015

机译：绿色高分子化学：研究3,6-Dioxa-1,8-辛二硫醇（DODT）的自由基开环氧化还原聚合反应机理（R3p）

Current Trends in the Development of Investigations into the Microheterogeneous Mechanism of Three-Dimensional Radical Polymerization

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