Structure of Methane Complexes According to the Data of Experimental and Theoretical Investigations

V.D.Makhaev

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Structure of Methane Complexes According to the Data of Experimental and Theoretical Investigations

机译：根据实验和理论研究数据的甲烷配合物的结构

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The results of experimental and theortical research of the structurs of methane complexes with neutral metal atoms,M~+ cations and ML_n molecular fragments are considered and generalised.The influence of the charge and electronic configuration of central atoms,the nature of stabilising ligands L on the mode of coordination of methane in complexes is analysed.The data of theoretical calculations of the structurs of methane complexes are compared with results of structural research of some classes of model compounds-borane complexes M(CO)_5.BH_3L(M=Cr,Mo,W),thtrahydroborate complexes ML_n(BH_4)_m,containing BH_4~- anions as ligands.Some regularities determining the model of coordination of methane in complexes are identified and assumptions about dependence of the modes of coordination of methane on the electronic configuration of the central atom are made.

机译：考虑并推广了中性金属原子，M〜+阳离子和ML_N分子片段的甲烷配合物结构的实验和主动脉研究的结果。中枢原子的电荷和电子配置的影响，稳定配体L的性质分析复合物中甲烷的配位模式。将甲烷配合物的结构的理论计算数据与某些类别类化合物 - 硼烷配合物M（CO）_5.BH_3L（M = Cr， Mo，W），含有BH_4〜 - 阴离子的MO，W），含有BH_4〜阴离子作为配体。确定甲烷在复合物中配位配位模型的核心规律以及关于甲烷协调模式的依赖性的假设中央原子是制作的。

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《Успехи химии》 |2003年第3期|共24页
作者
V.D.Makhaev;
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Institute of Problems of Chemical Physics Russian Academy of Sciences 142432 Chernogolovka Moscow Region Russian Federation;

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中图分类化学;
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1. Structure of methane complexes according to the data of experimental and theoretical investigations [J] . V D Makhaev Russian Chemical Reviews: Reviews on Current Topics in Chemistry . 2003,第3期

机译：甲烷配合物的结构根据实验和理论研究的数据
2. Structure of Methane Complexes According to the Data of Experimental and Theoretical Investigations [J] . V.D.Makhaev Успехи химии . 2003,第3期

机译：根据实验和理论研究数据的甲烷配合物的结构
3. Interplay between C-H center dot center dot center dot O, O-H center dot center dot center dot X (X = C, F, Cl) and H-O center dot center dot center dot Y (C, Cl, F) interactions in methane-water and halogen substituted methane-water complexes: Theoretical investigations of structure and energy [J] . Mukhopadhyay Anamika Computational & theoretical chemistry . 2016,第Null期

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4. Experimental and theoretical investigation of the conducting properties of ordered layers of crown ether complexes with Li+ ions on the lithium anode surface [C] . Tulibaeva G.Z., Yudina A.V., Shestakov A.F. International Conference on BRNO Advanced Batteries, Accumulators and Fuel Cells . 2013

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Structure of Methane Complexes According to the Data of Experimental and Theoretical Investigations

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