TWO NEW ENTANGLED Zn AND Cd COORDINATION POLYMERS BASED ON A RICH МIХ FEATURE OF THE O- AND N-DONOR LIGAND SYSTEM: SYNTHESIS, STRUCTURE, AND FLUORESCENT PROPERTIES

X.F. Wang

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TWO NEW ENTANGLED Zn AND Cd COORDINATION POLYMERS BASED ON A RICH МIХ FEATURE OF THE O- AND N-DONOR LIGAND SYSTEM: SYNTHESIS, STRUCTURE, AND FLUORESCENT PROPERTIES

机译：基于富含“Мiх”的两种新的缠结ZN和CD配位聚合物的O-和N-供体配体系统的特征：合成，结构和荧光特性

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A prominent mixed-ligand system with rich mix features, which are rigid multicarboxylate O-donor ligands cooperating with flexible bisazole N-donor linkers, is explored to coordinate with Zn2+/Cd2+ centers. Two new entangled coordination polymers ([Cd(Hbtc)(bbi)J (1) and [Zn(btec)0.5(dtp)] · 5H2O (2)) are gained. Complex 1 exhibits a fascinating 3D (3,5)-connected net with a Schlafli symbol of the (6~3.6~10) topology, and 3D nets penetrate into each other to give rise to twofold interpenetrations. Complex 2 displays a 2D layer with similar 9.9x12.0A2 hexagonal channels, the adjacent layers stacking with each other to form a 3D supramolecular structure. The effects and functions of the ligands in the complexes are discussed. Moreover, the thermal stabilities and fluorescence properties of complexes 1 and 2 are investigated.

机译：具有富含富含苯甲钛N-供体接头配合的富含富含多羧酸溶胶o-供体配体的突出的混合配体系统，探讨了与Zn2 + / CD2 +中心坐标。获得了两个新的缠结配位聚合物（[Cd（HBTC）（BBI）J（1）和[Zn（BTEC）0.5（DTP）]·5H 2 O（2））。复合体1展示了一个迷人的3D（3,5）连接的网，其中3〜3〜3〜10）拓扑的Schlafli符号，3D网彼此渗透以产生双重渗透。复杂2显示具有类似9.9x12.0a2六边形通道的2d层，相邻的层彼此堆叠以形成3d超分子结构。讨论了配合物中配体的效果和功能。此外，研究了复合物1和2的热稳定性和荧光性质。

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《Журнал струκтурной химии》 |2020年第6期|共9页
作者
X.F. Wang;
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作者单位

State Key Laboratory of Titanium and Vanadium Testing Panzhihua University Panzhihua P. R. China;

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原文格式 PDF
正文语种 eng
中图分类结构化学;
关键词
coordination polymer; luminescent property; hydro thermal synthesis; interdigi-tation.;

机译：配位聚合物;发光财产;水力热合成;interdigi-tation。;

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1. TWO NEW ENTANGLED Zn AND Cd COORDINATION POLYMERS BASED ON A RICH МIХ FEATURE OF THE O- AND N-DONOR LIGAND SYSTEM: SYNTHESIS, STRUCTURE, AND FLUORESCENT PROPERTIES [J] . X.F. Wang Журнал струκтурной химии . 2020,第6期

机译：基于富含“Мiх”的两种新的缠结ZN和CD配位聚合物的O-和N-供体配体系统的特征：合成，结构和荧光特性
2. Solvothermal syntheses, structures and fluorescent properties of six Zn-II/Cd-II coordination polymers constructed from N-donor ligands and multidentate organic acid [J] . Dong Jun-Liang, Xie Fei, Du Jia-Qiang, Journal of Solid State Chemistry . 2019,第期

机译：六ZN-II / CD-II配位聚合物的溶剂热合成，结构和荧光特性由N-供体配体构成和多型有机酸构成
3. A novel Zn(II) coordination polymer based on tetra-carboxylates ligand and N-donor ligand: synthesis, structure and photocatalytic properties [J] . Wang Shu-Long, Huang Wen-Fang, Wei Qing-Min, Molecular crystals and liquid crystals . 2018,第期

机译：基于四羧酸盐配体和N-供体配体的新型Zn（II）配位聚合物：合成，结构和光催化性能
4. Synthesis and Crystal Structure of a Novel Coordination Polymer Cd(en)(NO3)2(4,4'-bpy)nContaining Three Kinds of Ligands [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：包含三种配体的新型配位聚合物Cd（en）（NO3）2（4,4'-bpy） n的合成和晶体结构
5. Synthesis, structure and reactivity of transition metal complexes containing P-, O- and N-donor ligands [D] . Kuznetsov, Vladimir F. 2001

机译：含P，O和N供体配体的过渡金属配合物的合成，结构和反应活性
6. From 1D to 2D Cd(II) and Zn(II) Coordination Networks by Replacing Monocarboxylate with Dicarboxylates in Partnership with Azine Ligands: Synthesis Crystal Structures Inclusion and Emission Properties [O] . Victor Ch. Kravtsov, Vasile Lozovan, Nikita Siminel, 2020

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7. Zn(II) and Cd(II) Coordination Dimers Based on Mixed Benzodioxole-Carboxylate and N-Donor Ligands: Synthesis, Characterization, Crystal Structures and Photoluminescence Properties [O] . Miguel Guerrero, Sergio Vázquez, José A. Ayllón, 2017

机译：Zn（II）和Cd（II）基于混合苯二佐甲醛 - 羧酸盐和N-供体配体的配位二聚体：合成，表征，晶体结构和光致发光性能

TWO NEW ENTANGLED Zn AND Cd COORDINATION POLYMERS BASED ON A RICH МIХ FEATURE OF THE O- AND N-DONOR LIGAND SYSTEM: SYNTHESIS, STRUCTURE, AND FLUORESCENT PROPERTIES

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