C-H and C-M Activation, Aromaticity Tuning, and Co···Ru Interactions Confined in the Azuliporphyrin Framework

Micha? J. Bia?ek; Piotr J. Chmielewski; Lechos?aw Latos-Gra?yński

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C-H and C-M Activation, Aromaticity Tuning, and Co···Ru Interactions Confined in the Azuliporphyrin Framework

机译：C-H和C-M激活，芳香性调谐，以及CO ... ru互动在紫红素框架内限制

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Taking advantage of the specific properties of azuliporphyrin and the reactivity of cobalt(II), activation of an azulene C(sp2)-H bond occurred and organometallic complexes with Co-C bonding were formed. The system allowed for macrocyclic aromaticity tuning through metal coordination and oxidation. Thanks to the CoII-C and parallel tested CuII-C reactivity and the affinity of metal centers to dioxygen, oxygen atom insertion into the M-C bond could be investigated. Insertion starts with an oxygen molecule coordination and leads to monomeric and dimeric complexes of specific electronic structures. Formation of unique paramagnetic s/p-hybrid bimetallic complexes enabled spectroscopic and theoretical investigations of peculiar CoII···Ru0 interactions.

机译：利用含吡啉的特异性和钴（II）的反应性，形成氮素C（SP2）-H键的活化和具有CO-C键合的有机金属配合物。该系统允许通过金属配位和氧化进行大环芳香性调整。由于COII-C和并联测试的CUII-C反应性和金属中心对二恶英的亲和力，可以研究氧原子插入M-C键。插入以氧分子配位开始，并导致特定电子结构的单体和二聚体复合物。形成独特的顺磁性S / P杂化双金属配合物的思维和理论研究的特殊COII···ru0相互作用。

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来源
《Chemistry: A European journal》 |2019年第64期|共10页
作者
Micha? J. Bia?ek; Piotr J. Chmielewski; Lechos?aw Latos-Gra?yński;
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作者单位

Department of Chemistry University of Wroc?aw F. Joliot-Curie 14 50-383 Wroc?aw (Poland);

Department of Chemistry University of Wroc?aw F. Joliot-Curie 14 50-383 Wroc?aw (Poland);

Department of Chemistry University of Wroc?aw F. Joliot-Curie 14 50-383 Wroc?aw (Poland);

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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
activation; azulene; carbaporphyrinoid; cobalt; ruthenium clusters;

机译：活化;氮素;碳酸卟啉;钴;钌簇;

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1. C-H and C-M Activation, Aromaticity Tuning, and Co···Ru Interactions Confined in the Azuliporphyrin Framework [J] . Micha? J. Bia?ek, Piotr J. Chmielewski, Lechos?aw Latos-Gra?yński Chemistry: A European journal . 2019,第64期

机译：C-H和C-M激活，芳香性调谐，以及CO ... ru互动在紫红素框架内限制
2. Aromatic C-H center dot center dot center dot pi, C-H center dot center dot center dot O and parallel aromatic-aromatic interactions in the crystal structure of meso-tetrakis[4-(benzyloxy)phenyl]porphyrin [J] . Kus Piotr, Kusz Joachim, Ksiazek Maria Journal of chemical crystallography . 2020,第1期

机译：芳香族C-H中心点中心点中心点PI，C-H中心点中心点中心点O和平行芳香族 - 芳族芳族相互作用中的晶体结构[4-（苄氧基）苯基]卟啉
3. Ru(Ⅱ)-Catalyzed spirocyclization of aryl N-sulfonyl ketimines with aryl isocyanates through an aromatic C-H bond activation [J] . Nagarjuna Reddy K, Subhadra U, Sridhar B, Organic & biomolecular chemistry . 2018,第14期

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4. Ru/CeO2-Catalyzed C-C Bond Forming Reactions via Aromatic C-H Bond Activation [C] . Kenji Wada, Hiroki Miura, Saburo Hosokawa Symposium on Organometallic Chemistry . 2008

机译：Ru / CeO2催化的C-C键通过芳族C-H键活化形成反应
5. Tuning Electrostatic Interactions in Confined Soft Matter [D] . Gebbie, Matthew Allen. 2016

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6. Tuning Light Emission towards White Light from a Naphthalenediimide-Based Entangled Metal-Organic Framework by Mixing Aromatic Guest Molecules [O] . Rebeca Sola-Llano, Virginia Martínez-Martínez, Shuhei Furukawa, 2018

机译：通过混合芳香客体分子使基于萘二甲酰亚胺的纠缠金属有机框架向白光发射光调谐。
7. 4-bromo-beta-(2-oxoquinolin-4-yloxy)cinnamonitrile: a three-dimensional framework structure built from N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds, and bromo-carbonyl and aromatic pi-pi stacking interactions [O] . Cruz, Silvia, de la Torre, Jose M., Cobo, Justo, 2006

机译：4-溴-β-（2-氧代喹啉-4-基氧基）肉桂腈：由NH中心点中心点中心点O和CH中心点中心点中心点O的氢键，溴代羰基和芳香pi-pi堆积相互作用

C-H and C-M Activation, Aromaticity Tuning, and Co···Ru Interactions Confined in the Azuliporphyrin Framework

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