Hydrolysis of a basic bismuth nitrate-formation and stability of novel bismuth oxido clusters

Miersch L.; Schlesinger M.; Troff R.W.; Schalley C.A.; Rüffer T.; Lang H.; Zahn D.; Mehring M.

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Hydrolysis of a basic bismuth nitrate-formation and stability of novel bismuth oxido clusters

机译：水解碱性硝酸铋形成和新型铋簇的稳定性

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The synthesis of the nanoscaled bismuth oxido clusters [Bi _(38)O_(45)- (NO_3)_(20)(DMSO) _(28)](NO_3)_4·4 DMSO (1 a) and [Bi _(38)O_(45)(OH)_2(pTsO)_8- (NO _3)_(12)(DMSO)_(24)](NO_3) _2·4 DMSO· 2 H_2O (2) starting from the basic bismuth nitrate [Bi_6O_4(OH)_4](NO _3)_6·H_2O is reported herein. Single-crystal X-ray diffraction analysis, ESI mass spectrometry, thermogravimetric analysis, and molecular dynamics simulation were used to study the formation, structure, and stability of these large metal oxido clusters. Compounds 1 a and 2 are based on a [Bi_(38)O_(45)]~(24+) core, which is structurally related to δ-Bi_2O_3. Examination of the fragmentation pathways of 1 a and 2 by infrared multi-photon dissociation (IRMPD) tandem MS experiments allows the identification of novel bismuth oxido cluster species in the gas phase.

机译：氧化铋簇的合成[Bi _（38）O_（45） - （NO_3）_（20）（DMSO）_（28）]（NO_3）_4·4 DMSO（1A）和[BI _（ 38）O_（45）（OH）_2（PTSO）_8-（NO _3）_（12）（DMSO）_（DMSO）_（24）]（NO_3）_2·4 DMSO·2 H_2O（2）从硝酸盐的基本铋开始 [Bi_6O_4（OH）_4]（NO _3）_6·H_2O在此报告。单晶X射线衍射分析，ESI质谱，热重分析和分子动力学模拟用于研究这些大型金属氧化群簇的形成，结构和稳定性。化合物1a和2基于[Bi_（38）O_（45）]〜（24+）核，其与Δ-BI_2O_3在结构上有关。通过红外多光子解离（IRMPD）串联MS实验检测1a和2的碎片途径允许鉴定气相中的新型铋氧化簇种类。

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《Chemistry: A European journal》 |2011年第25期|共6页
作者
Miersch L.; Schlesinger M.; Troff R.W.; Schalley C.A.; Rüffer T.; Lang H.; Zahn D.; Mehring M.;
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作者单位

Technische Universit?t Chemnitz Strasse der Nationen 62 09111 Chemnitz Germany;

Technische Universit?t Chemnitz Strasse der Nationen 62 09111 Chemnitz Germany;

Institut für Chemie und Biochemie Freie Universit?t Berlin Takustrasse 3 14195 Berlin Germany;

Institut für Chemie und Biochemie Freie Universit?t Berlin Takustrasse 3 14195 Berlin Germany;

Technische Universit?t Chemnitz Strasse der Nationen 62 09111 Chemnitz Germany;

Technische Universit?t Chemnitz Strasse der Nationen 62 09111 Chemnitz Germany;

Friedrich-Alexander-Universit?t Erlangen-Nürnberg N? gelsbachstrasse 25 91052 Erlangen Germany;

Technische Universit?t Chemnitz Strasse der Nationen 62 09111 Chemnitz Germany;

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正文语种 eng
中图分类应用化学;
关键词
bismuth nitrate; hydrolysis; mass spectrometry; metal oxido cluster; molecular dynamics;

机译：硝酸铋;水解;质谱;金属氧化群簇;分子动力学;

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1. Hydrolysis of a basic bismuth nitrate-formation and stability of novel bismuth oxido clusters [J] . Miersch L., Schlesinger M., Troff R.W., Chemistry: A European journal . 2011,第25期

机译：水解碱性硝酸铋形成和新型铋簇的稳定性
2. From a Bismuth Oxido Diketonate to a Giant Bismuth Oxido Cluster [J] . Evgeny V.Dikarev, Haitao Zhang, Bo Li Angewandte Chemie . 2006,第33期

机译：从氧化铋二酮酸铋到巨型氧化铋簇
3. Bismuth(Ⅲ) benzohydroxamates: powerful antibacterial activity against Helicobacter pylori and hydrolysis to a unique Bi_(34) oxido-cluster [Bi_(34)O_(22)(BHA)_(22)(H-BHA)_(14)(DMSO)_6] [J] . Amita Pathak, Victoria L. Blair, Richard L. Ferrero, Chemical Communications . 2014,第96期

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4. 1.5 S-Butyl 1.5 N-Butyl Bismuth and 1.5-Butyl 1.5-Isopropyl Bismuth as new Liquid Bismuth Precursors for SBT Thin Film Deposition [C] . S. Matichyn, M. Lisker, M. Silinskas, Meeting of the Electrochemical Society . 2007

机译：1.5叔丁基1.5丁基铋和1.5丁基1.5-异丙基铋作为SBT薄膜沉积的新型液体铋前体
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

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6. Thin Coatings of α‐ and β‐Bi2O3 by Ultrasonic Spray Coating of a Molecular Bismuth Oxido Cluster and their Application for Photocatalytic Water Purification Under Visible Light [O] . Max Hofmann, Leonard Rößner, Prof. Dr. Marc Armbrüster, 2020

机译：通过超声波喷涂的α-和β-Bi2O3的薄涂层通过超声喷涂氧化胺簇及其在可见光下的光催化水净化应用
7. Bismuth(III) benzohydroxamates: powerful anti-bacterial activity against Helicobacter pylori and hydrolysis to a unique Bi34 oxido-cluster Bi34O22(BHA)22(H-BHA)14(DMSO)6 [O] . Pathak Amita, Blair Victoria L., Ferrero Richard L., 2015

机译：苯并异羟肟酸铋（III）：对幽门螺杆菌具有强大的抗菌活性，可水解成独特的Bi34氧化簇Bi34O22（BHA）22（H-BHA）14（DMSO）6

Hydrolysis of a basic bismuth nitrate-formation and stability of novel bismuth oxido clusters

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