Comparative Study of Metal-Catalyzed limitations of Sulfoxides and Sulfides

Olga Garcia Mancheno; Carsten Bolm

首页> 外文期刊>Chemistry: A European journal >Comparative Study of Metal-Catalyzed limitations of Sulfoxides and Sulfides

【24h】

Comparative Study of Metal-Catalyzed limitations of Sulfoxides and Sulfides

机译：金属催化亚砜和硫化物局限性的比较研究

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A comparative study of the imination of sulfur compounds with various metal catalysts in combination with isolated or in situ generated imi-noiodinanes (PhI=NR) as nitrogen sources is presented.The influence of the metal catalyst towards the imination of a variety of substituted sulfoxides has been evaluated.Moreover,the effect of the different oxidation states of sulfur on the reactivity and selectivity of the nitrogen transfer redox process in the formation of sulfilimines and sulfoximines was studied.Depending on both the specific metal catalyst as well as the employed nitrene precursor,the sulfide/sulfoxide imination ratio varied in transformations of thianthrene-5-oxide and substituted para-thio phenylsulfoxides.

机译：提出了与分离的或原位产生的各种金属催化剂的硫化合物的化合物的对比研究作为氮源的组合。金属催化剂对各种取代的亚砜的化学性的影响已经评估了，研究了不同氧化态对氮转移氧化还原方法的反应性和选择性在形成亚磺脒和亚磺酰胺的反应性和选择性的影响。在特定金属催化剂以及所用的硝基前体上进行了研究，硫化物/亚硫氧化物的化学率在于氧化物 - 5-氧化物的转化和取代的对硫代苯磺酰氧化物的转化中变化。

著录项

来源
《Chemistry: A European journal》 |2007年第23期|共8页
作者
Olga Garcia Mancheno; Carsten Bolm;
展开▼
作者单位

Institute of Organic Chemistry RWTH Aachen University Landoltweg 1 52056 Aachen (Germany);

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
homogeneous catalysis; iminations; sulfilimines; sulfoximines; sulfur;

机译：均匀催化;亚胺;磺胺酸亚胺;硫酸亚胺;硫磺;

相似文献

外文文献
中文文献
专利

1. Comparative Study of Metal-Catalyzed limitations of Sulfoxides and Sulfides [J] . Olga Garcia Mancheno, Carsten Bolm Chemistry: A European journal . 2007,第23期

机译：金属催化亚砜和硫化物局限性的比较研究
2. Formation of diaryl sulfides and sulfoxides: Synthesis, characterization and structure activity correlation studies [J] . Lamani Devappa S., Badiger Srikant G., Singh Mamata Phosphorus, Sulfur, and Silicon and the Related Elements . 2019,第7a9期

机译：二芳基硫化物和亚砜的形成：合成，表征和结构活性相关研究
3. Combined theoretical and experimental study on the adsorption mechanism of poly(4-vinylbenzyl 2-hydroxyethyl) sulfide, sulfoxide, and sulfone for Hg(II) and Pb(II) [J] . Niu Yuzhong, Zhao Shigui, Chen Guowen, Journal of Molecular Liquids . 2016,第Null期

机译：聚（4-乙烯基苄基2-羟乙基）硫化物，亚砜和砜对Hg（II）和Pb（II）的吸附机理的理论和实验研究相结合
4. (593586)A COMPARATIVE STUDY OF COPPER RECOVERY FROM DIFFERENT PRIMARY COPPER-SULFIDE ORES WITH JX IODINE PROCESS [C] . Akira Miura, Yuken Fukano, Katsuyuki Sato Annual Conference of Metallurgists . 2019

机译：（593586）用JX碘工艺从不同硫化铜 - 硫化物矿石中铜回收的比较研究
5. STUDIES IN ORGANOSULFUR CHEMISTRY. I. NUCLEAR MAGNETIC RESONANCE (PROTON, CARBON-13, OXYGEN-17 (1) J(C-H)) INVESTIGATIONS OF ORGANOSULFUR COMPOUNDS. II. MECHANISTIC STUDY OF PHASE TRANSFER CATALYZED REACTIONS OF DICHLOROCARBENE WITH SULFIDES AND SULFOXIDES. III. STUDIES DIRECTED TOWARD ASYMMETRIC SYNTHESIS USING CHIRAL PHASE TRANSFER CATALYSTS. [D] . DYER, JOHN COLLINS. 1980

机译：有机硫化学研究。 I.有机硫化合物的核磁共振（质子，碳13，氧17（1）J（C-H））研究。二。二氯卡宾与硫化物和硫化物的相转移催化反应的机理研究。三，使用手性相转移催化剂进行不对称合成的研究。
6. Effects of Dimethyl Sulfoxide in Cholesterol-Containing Lipid Membranes: A Comparative Study of Experiments In Silico and with Cells [O] . Marie-Amélie de Ménorval, Lluis M. Mir, M. Laura Fernández, 2009

机译：二甲基亚砜在含胆固醇脂质膜中的作用：计算机和细胞实验的比较研究
7. Synthesis and Characterization of Sulfamic Acid-Functionalized Nanoparticles and Study of Its Catalytic Activity for the Oxidation of Sulfides to Sulfoxides [O] . Ghorbani-Choghamarani, Arash, Azadi, Gouhar 2016

机译：氨基磺酸官能化纳米粒子的合成，表征及其催化硫化物氧化成亚砜的催化活性的研究
8. P-Chlorophenyl Methyl Sulfide, p-Chlorophenyl Methyl Sulfoxide, and p-Chlorophenyl Methyl Sulfone. 1. Acute Toxicity and Bacterial Mutagenicity Studies [R] . Leber, A. P., Dacre, J. C., Thake, D. C., 1993

机译：对氯苯基甲基硫醚，对氯苯基甲基亚砜和对氯苯基甲基砜。 1.急性毒性和细菌致突变性研究

Comparative Study of Metal-Catalyzed limitations of Sulfoxides and Sulfides

摘要

著录项

相似文献

相关主题

期刊订阅