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Guest-Dependent Spin-Transition Behavior of Porous Coordination Polymers

机译:多孔协调聚合物的客观依赖性旋转过渡行为

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摘要

The host-guest composites of Hofmann-type iron(II) spin-transition (ST) porous coordination polymers incorporating guest molecules show guest-dependent ST behavior in accordance with the respective guest species, which may be a gas, solvent, halogen, or organic molecule. The guest also works as a chemical stimulant to switch the spin state of the host between high and low spin at room temperature. In this review, we discuss guest properties including size, shape, flexibility, chemical properties, and pore loading content, which impact the spin states of the host framework and the ST behavior exhibited by the host-guest composites.
机译:Hofmann型铁(II)的宿主复合材料(II)旋转过渡(ST)多孔配位聚合物,其包含来自各自的客体物种,其可以是气体,溶剂,卤素或 有机分子。 客人还用作化学兴奋剂,以在室温下在高旋转和低旋转之间切换宿主的旋转状态。 在本文中,我们讨论了客户属性,包括大小,形状,灵活性,化学性质和孔隙加载内容,它影响了主机框架的旋转状态和主机复合材料所展示的ST行为。

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