'Trojan Horse' Effect in Photocatalysis-How Anionic Silver Impurities Influence Apparent Catalytic Activity

Simon Kaufhold; Lydia Petermann; Dieter Sorsche; Sven Rau

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'Trojan Horse' Effect in Photocatalysis-How Anionic Silver Impurities Influence Apparent Catalytic Activity

机译：“特洛伊马”在光催化中的影响 - 阴离子银杂质如何影响表观催化活性

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The problematic consequences of using silver carbene precursors for the synthesis of NHC-complexes is elucidated with the example of dinuclear Ru-Rh/Ir photocatalysts. The presence of silver in the products is proven and an alternative silver-free synthetic approach successfully implemented. A significant difference in performance in photocatalytic hydrogen evolution reactions of catalysts generated by the different strategies is observed.

机译：用硫卫RU-RH / IR光催化剂的实施例阐明了使用用于合成NHC-络合物的银菜前体的问题后果。已验证产品中银的存在，并成功实施了另类无银色的合成方法。观察到不同策略产生的催化剂的光催化氢演化反应中的性能显着差异。

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来源
《Chemistry: A European journal》 |2017年第10期|共4页
作者
Simon Kaufhold; Lydia Petermann; Dieter Sorsche; Sven Rau;
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作者单位

Inorganic Chemistry I Ulm University Albert-Einstein-Allee 11 8908 Ulm (Germany);

Inorganic Chemistry I Ulm University Albert-Einstein-Allee 11 8908 Ulm (Germany);

Inorganic Chemistry I Ulm University Albert-Einstein-Allee 11 8908 Ulm (Germany);

Inorganic Chemistry I Ulm University Albert-Einstein-Allee 11 8908 Ulm (Germany);

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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
impurities; N-heterocyclic carbenes; photocatalysis; silver; water splitting;

机译：杂质;N-杂环碳;光催化;银;水分裂;

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1. "Trojan Horse" Effect in Photocatalysis-How Anionic Silver Impurities Influence Apparent Catalytic Activity [J] . Simon Kaufhold, Lydia Petermann, Dieter Sorsche, Chemistry: A European journal . 2017,第10期

机译：“特洛伊马”在光催化中的影响 - 阴离子银杂质如何影响表观催化活性
2. Effects of cationic and anionic micelles on the morphology of biogenic silver nanoparticles, and their catalytic activity for congo red [J] . Zaheer Zoya, Aazam Elham Shafik, Kosa Samia A. Journal of Molecular Liquids . 2016,第Null期

机译：阳离子和阴离子胶束对生物银纳米颗粒形态的影响及其对刚果红的催化活性
3. TRANSPLANTING A POLYCYSTIC KIDNEY-TROJAN HORSE OR SILVER LINING? [J] . Malhotra Kunal, Abuzeineh Mohammad, Dalal Pranav American Journal of Kidney Diseases: The official journal of the National Kidney Foundation . 2019,第5期

机译：移植多囊肾木马或银衬里？
4. Multi-Compsnent Flame Retardants: Combining Anionic and Cationic Clays as Trojan Horses for Molecular Flame Retardants [C] . Bashar Diar-Bakerly, Josef Hausner, Hussein Kalo Conference on Recent Advances in Flame Retardancy of Polymeric Materials . 2015

机译：多Complnnent阻燃剂：将阴离子和阳离子粘土结合为分子阻燃剂的特洛伊木马
5. Activity and stability of silver-alumina catalysts for the selective catalytic reduction of nitric oxides with methane. [D] . She, Xiaoyan. 2006

机译：银-氧化铝催化剂对甲烷选择性催化还原一氧化氮的活性和稳定性。
6. Anionic block copolymer vesicles act as Trojan horses to enable efficient occlusion of guest species into host calcite crystals [O] . Yin Ning, Daniel J. Whitaker, Charlotte J. Mable, 2018

机译：阴离子嵌段共聚物囊泡可充当特洛伊木马从而有效地将客体物种吸附到方解石晶体中
7. A trojan horse in Daoguang China? Explaining the flows of silver in and out of China [O] . Irigoin Maria Alejandra 2013

机译：中国道光的木马？解释白银流入和流出中国的情况

'Trojan Horse' Effect in Photocatalysis-How Anionic Silver Impurities Influence Apparent Catalytic Activity

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