Soluble Two-Dimensional Covalent Organometallic Polymers by (Arene)Ruthenium-Sulfur Chemistry

Johann Coraux; Wael Hourani; Valentin L. Meller; Simon Lamare; Danial Aiman Kamaruddin; Laurence Magaud; Nedjma Bendiab; Martien Den Hertog; Olivier Leynaud; Frank Palmino; Roland Salut; Frédéric Chérioux

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Soluble Two-Dimensional Covalent Organometallic Polymers by (Arene)Ruthenium-Sulfur Chemistry

机译：通过（芳烃）钌 - 硫化学溶于二维共价有机金属聚合物

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A class of two-dimensional (2D) covalent organometallic polymers, with nanometer-scale crosslinking, was obtained by arene(ruthenium) sulfur chemistry. Their ambivalent nature, with positively charged crosslinks and lypophylic branches is the key to the often sought-for and usually hard-to-achieve solubility of 2D polymers in various kinds of solvents. Solubility is here controlled by the planarity of the polymer, which in turn controls Coulomb interactions between the polymer layers. High planarity is achieved for high symmetry crosslinks and short, rigid branches. Owing to their solubility, the polymers are easily processable, and can be handled as powder, deposited on surfaces by mere spin-coating, or suspended across membranes by drop-casting. The novel 2D materials are potential candidates as flexible membranes for catalysis, cancer therapy, and electronics.

机译：通过芳烃（Ruthenium）硫化学获得，一类具有纳米级交联的二维（2D）共价有机金属聚合物。他们的矛盾性质，带有带正电荷的交联和障碍枝是经常寻求的主要和通常在各种溶剂中的2D聚合物的溶解度的关键。这里溶解度由聚合物的平坦性控制，这反过来控制聚合物层之间的库仑相互作用。高对称交联和短，刚性分支实现高平面度。由于它们的溶解度，聚合物易于加工，并且可以作为粉末处理，通过仅仅通过旋涂沉积在表面上，或通过滴浇铸悬浮在膜上。新型2D材料是潜在的候选者，作为催化膜，癌症治疗和电子产品。

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来源
《Chemistry: A European journal》 |2017年第46期|共5页
作者
Johann Coraux; Wael Hourani; Valentin L. Meller; Simon Lamare; Danial Aiman Kamaruddin; Laurence Magaud; Nedjma Bendiab; Martien Den Hertog; Olivier Leynaud; Frank Palmino; Roland Salut; Frédéric Chérioux;
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作者单位

Univ. Grenoble Alpes 38000 Grenoble (France) CNRS &

Inst NEEL 38042 Grenoble (France);

Institut FEMTO-ST 15B avenue des Montboucons CNRS Université Bourgogne Franche-Comt8 25030 Besancon Cedex (France);

Univ. Grenoble Alpes 38000 Grenoble (France) CNRS &

Inst NEEL 38042 Grenoble (France);

Institut FEMTO-ST 15B avenue des Montboucons CNRS Université Bourgogne Franche-Comt8 25030 Besancon Cedex (France);

Institut FEMTO-ST 15B avenue des Montboucons CNRS Université Bourgogne Franche-Comt8 25030 Besancon Cedex (France);

Univ. Grenoble Alpes 38000 Grenoble (France) CNRS &

Inst NEEL 38042 Grenoble (France);

Univ. Grenoble Alpes 38000 Grenoble (France) CNRS &

Inst NEEL 38042 Grenoble (France);

Univ. Grenoble Alpes 38000 Grenoble (France) CNRS &

Inst NEEL 38042 Grenoble (France);

Univ. Grenoble Alpes 38000 Grenoble (France) CNRS &

Inst NEEL 38042 Grenoble (France);

Institut FEMTO-ST 15B avenue des Montboucons CNRS Université Bourgogne Franche-Comt8 25030 Besancon Cedex (France);

Institut FEMTO-ST 15B avenue des Montboucons CNRS Université Bourgogne Franche-Comt8 25030 Besancon Cedex (France);

Institut FEMTO-ST 15B avenue des Montboucons CNRS Université Bourgogne Franche-Comt8 25030 Besancon Cedex (France);

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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
(arene)ruthenium-sulfur chemistry; materials science; nanotechnology; organometallic compound; polymers;

机译：（芳烃）钌 - 硫化学;材料科学;纳米技术;有机金属化合物;聚合物;

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1. Soluble Two-Dimensional Covalent Organometallic Polymers by (Arene)Ruthenium-Sulfur Chemistry [J] . Johann Coraux, Wael Hourani, Valentin L. Meller, Chemistry: A European journal . 2017,第46期

机译：通过（芳烃）钌 - 硫化学溶于二维共价有机金属聚合物
2. Combining hydrogen bonds with coordination chemistry or organometallic #pi#-arene chemistry: strategies for inorganic crystal engineering [J] . Lee Brammer, Juan C. Mareque Rivas, Reinaldo Atencio, Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2000,第21期

机译：将氢键与配位化学或有机金属＃pi＃-芳烃化学结合：无机晶体工程的策略
3. Organometallic chemistry,biology and medicine:ruthenium arene anticancer complexes [J] . Yaw Kai Yan, Michael Melchart, Abraha Habtemariam, Chemical Communications . 2005,第38期

机译：有机金属化学，生物学和医学：钌芳烃抗癌复合物
4. From Organometallic and Polymer Chemistry to Applied Materials Science: Transition Metal Catalyzed Synthesis of Polyolefins and Polyolefin-Based High-Performance Materials [C] . Michael R. Buchmeiser, Macromolecular Symposia 181 Conference on Osterreichische polymertage . 2002

机译：从有机金属和聚合物化学到应用材料科学：过渡金属催化聚烯烃合成合成聚烯烃和聚烯烃高性能材料
5. Organometallic chemistry of eta(6)-aromatic-cyclic-hydrocarbon manganese tricarbonyl complexes and electrochemical study of (arene)Cr(CO)(3) complexes having a pendent ferrocenyl switch. [D] . Yeung, Lee Kon. 1998

机译：η（6）-芳香族环烃三羰基锰锰配合物的有机金属化学和具有二茂铁基悬垂开关的（arene）Cr（CO）（3）配合物的电化学研究。
6. PMMA-Etching-Free Transfer of Wafer-scale Chemical Vapor Deposition Two-dimensional Atomic Crystal by a Water Soluble Polyvinyl Alcohol Polymer Method [O] . Huynh Van Ngoc, Yongteng Qian, Suk Kil Han, -1

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7. Soluble Two-Dimensional Covalent Organometallic Polymers by (Arene)Ruthenium-Sulfur Chemistry [O] . Coraux, Johann, Hourani, Wael, Müller, Valentin,, 2017

机译：（Arene）钌-硫化学法研究可溶性二维共价有机金属聚合物
8. Studies in Ivth Group Organometallic Chemistry. Vi. Preparation and Polymerization of Ivth Group Organometallic Derivatives of Styrene and Methylstyrene [R] . Noltes, J. G., Budding, H. A., Van der Kerk, G. J. M. 1960

机译：第I组有机金属化学研究。六。苯乙烯和甲基苯乙烯第四组有机金属衍生物的制备及聚合

Soluble Two-Dimensional Covalent Organometallic Polymers by (Arene)Ruthenium-Sulfur Chemistry

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