New Bifunctional Metal-Organic Frameworks and Their Utilization in One-Pot Tandem Catalytic Reactions

Mistry Subhradeep; Sarkar Anupam; Natarajan Srinivasan

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New Bifunctional Metal-Organic Frameworks and Their Utilization in One-Pot Tandem Catalytic Reactions

机译：新的双官能金属有机框架及其在一锅串联催化反应中的利用

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Two new metal-organic framework (MOF) compounds were synthesized by a room temperature slow diffusion reaction. The compounds, [Cd-3(C8H3SO7)(2)-(C10H8N4)(3)( C3H7NO)(2)] ( C3H7NO)(2)center dot(CH3OH)(4), I, and [Cd-3(C8H3SO7)(2 )(C12H10N4)(3 )(C3H7NO)(2)] (C12H10N4)center dot(C3H7NO)(2), II, have comparable structures formed by Cd-sulfoisopthalate layers cross-linked by bipyridyl linkers forming three-dimensional structures. The compounds have both Lewis acidic (Cd metal centers) as well as basic (azine, free pyridine, and uncoordinated sulfo oxygens) sites, and they exhibited good catalytic activity for one-pot tandem deacetalization-Knoevenagel condensation reactions. The compounds exhibit catalytic activity both in the presence of a solvent as well as in solvent-free conditions. Compound I also exhibits good proton conductivity at room temperature.

机译：通过室温慢扩散反应合成了两种新的金属有机框架（MOF）化合物。化合物[CD-3（C8H3SO7）（2） - （C10H8N4）（3）（C 3 O）（2）（2）（2）中心点（CH 3 OH）（4），I和[CD-3（ C8H3SO7）（2）（2）（C12H10N4）（3）（C 3 ON 4）中心点（C12H10N4）中央点（C 3 ON 4）（2），II具有通过形成三吡啶接头交联的CD-磺基苯甲酸酯层形成的可比结构尺寸结构。该化合物具有路易斯酸性（Cd金属中心）以及碱性（吖嗪，游离吡啶和未配备的磺氧化物）位点，并且它们表现出良好的催化活性，用于单罐串联脱乙醚瘤结缩反应。化合物在溶剂存在下表现出催化活性以及无溶剂的条件。化合物I在室温下也表现出良好的质子电导率。

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《Crystal growth & design》 |2019年第2期|共9页
作者
Mistry Subhradeep; Sarkar Anupam; Natarajan Srinivasan;
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Indian Inst Sci Solid State &

Struct Chem Unit Framework Solids Lab Bangalore 560012 Karnataka India;

Indian Inst Sci Solid State &

Struct Chem Unit Framework Solids Lab Bangalore 560012 Karnataka India;

Indian Inst Sci Solid State &

Struct Chem Unit Framework Solids Lab Bangalore 560012 Karnataka India;

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正文语种 eng
中图分类晶体学;
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专利

1. New Bifunctional Metal-Organic Frameworks and Their Utilization in One-Pot Tandem Catalytic Reactions [J] . Mistry Subhradeep, Sarkar Anupam, Natarajan Srinivasan Nature reviews Cancer . 2019,第2期

机译：新的双官能金属 - 有机框架及其在一锅串联催化反应中的利用
2. New Bifunctional Metal-Organic Frameworks and Their Utilization in One-Pot Tandem Catalytic Reactions [J] . Mistry Subhradeep, Sarkar Anupam, Natarajan Srinivasan Crystal growth & design . 2019,第2期

机译：新的双官能金属有机框架及其在一锅串联催化反应中的利用
3. Synthesis and catalytic activities of a Zn(II) based metallomacrocycle and a metal-organic framework towards one-pot deacetalization-Knoevenagel tandem reactions under different strategies: a comparative study [J] . Dalton transactions: An international journal of inorganic chemistry . 2020,第24期

机译：Zn（II）基磷金属循环的合成与催化活性与不同策略下的单盆脱乙醛瘤的一盆脱乙醛串联反应的合成和催化活性：比较研究
4. Synthesis of Metal-Organic Framework-Derived Carbon Supported CoFe_2O_4 with Enhanced Oxygen Reduction Reaction Catalytic Properties [C] . Zongzhao Li, Jing Sui, Qian Zhang, Pacific Rim Meeting on Electrochemical and Solid-State Science . 2020

机译：用增强的氧还原反应催化性能合成金属 - 有机骨架衍生碳负载的COFE_2O_4
5. One-pot Tandem Diels-Alder/Nazarov Reactions to Generate Advanced Tricyclic Intermediates [D] . Carmichael, Rachael A. 2017

机译：一锅串联Diels-Alder / Nazarov反应生成高级三环中间体
6. Highly Efficient Bifunctional Amide Functionalized Zn and Cd Metal Organic Frameworks for One-Pot Cascade Deacetalization–Knoevenagel Reactions [O] . Anirban Karmakar, Anup Paul, Guilherme M. D. M. Rúbio, 2019

机译：高效的双官能酰胺官能化Zn和Cd金属有机框架用于单盆级联脱象 - knoevenagel反应
7. New Bifunctional Metal–Organic Frameworks and Their Utilization in One-Pot Tandem Catalytic Reactions [O] . Subhradeep Mistry, Anupam Sarkar, Srinivasan Natarajan 2018

机译：新的双官能金属 - 有机框架及其在一锅串联催化反应中的利用

New Bifunctional Metal-Organic Frameworks and Their Utilization in One-Pot Tandem Catalytic Reactions

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