Three Topological Isomers of 1D-and 2D-Coordination Polymers Consisting of Tricopper Pyrazolate SBUs and 4,4 '-Trimethylenedipyridine Linkers: Effect of Pressure on the Structure

Shi Kaige; Mathivathanan Logesh; Drozd Vadym A.; Raptis Raphael G.

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Three Topological Isomers of 1D-and 2D-Coordination Polymers Consisting of Tricopper Pyrazolate SBUs and 4,4 '-Trimethylenedipyridine Linkers: Effect of Pressure on the Structure

机译：由Tricopper吡唑酯SBUS和4,4'-三甲基吡啶接头组成的1D-and 2D配位聚合物的三种拓扑异构体：压力对结构的影响

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Three topologically isomeric coordination polymers of formula [Cu-3(II)(mu(3)-OH)(mu-Cl)(mu-pz)(3)Cl(tmpy)](n), consisting of triangular Cu-II-pyrazolate structural building units and flexible 4,4'-trimethylenedipyridine linkers, have been prepared and structurally characterized as 1D- and 2D-coordination polymers. Powder X-ray diffraction (PXRD) patterns under variable pressure (ambient, 8 GPa) reveal a reversible compression of the lattice up to similar to 4 GPa, followed by the loss of crystallinity at higher pressure. Single-crystal X-ray diffraction data, collected using synchrotron radiation under pressure of 1 GPa, corroborate the PXRD, showing a lattice compression forcing the C-C-C angles of the trimethylene moiety of the linkers to become more obtuse.

机译：三角形Cu-II的三种拓扑上异构配位聚合物的式[Cu-3（ii）（mu（3）-OH）（mu-cl）（mu-cl）（mu-pz）（3）cl（tmpy）]（n）组成 - 已经制备和结构表征为1D-和2D配位聚合物的制备和结构构建单元和柔性4,4'-三甲基吡啶接头。在可变压力（环境，8GPa）下粉末X射线衍射（PXRD）图案显示出晶格的可逆压缩，其相似至4GPa，然后在更高的压力下损失结晶度。单晶X射线衍射数据，使用同步辐射在1GPa的压力下收集，证实PXRD，显示晶格压缩，从而强制接头的三甲基部分的C-C-C角度变得更加钝。

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《Crystal growth & design》 |2019年第1期|共10页
作者
Shi Kaige; Mathivathanan Logesh; Drozd Vadym A.; Raptis Raphael G.;
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Florida Int Univ Dept Chem &

Biochem 11200 SW 8th St Miami FL 33199 USA;

Florida Int Univ Dept Chem &

Biochem 11200 SW 8th St Miami FL 33199 USA;

Florida Int Univ Ctr Study Matter Extreme Condit Miami FL 33199 USA;

Florida Int Univ Dept Chem &

Biochem 11200 SW 8th St Miami FL 33199 USA;

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正文语种 eng
中图分类晶体学;
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1. Three Topological Isomers of 1D-and 2D-Coordination Polymers Consisting of Tricopper Pyrazolate SBUs and 4,4 '-Trimethylenedipyridine Linkers: Effect of Pressure on the Structure [J] . Shi Kaige, Mathivathanan Logesh, Drozd Vadym A., Crystal growth & design . 2019,第1期

机译：由Tricopper吡唑酯SBUS和4,4'-三甲基吡啶接头组成的1D-and 2D配位聚合物的三种拓扑异构体：压力对结构的影响
2. X-Ray Crystal Structure of a Novel 2D Mn(II) Coordination Polymer with 4,4'-trimethylenedipyridine and 3-nitrophthalate as Ligands [J] . Chooset S., Kantacha A., Nimthong A., Journal of structural chemistry . 2018,第1期

机译：新型2D MN（II）配位聚合物的X射线晶体结构，具有4,4'-三甲基吡啶和3-硝基苯酸盐作为配体
3. X-RAY CRYSTAL STRUCTURE OF A NOVEL 2D Mn(II) COORDINATION POLYMER WITH 4,4'-TRIMETHYLENEDIPYRIDINE AND 3-NITROPHTHALATE AS LIGANDS [J] . S. Chooset, A. Kantacha, A. Nimthong, Журнал струκтурной химии . 2018,第1期

机译：新型2D MN（II）配位聚合物的X射线晶体结构，具有4,4'-三甲基吡啶和3-硝基苯酸盐作为配体
4. Zinc(II) and cadmium(II) coordination polymers containing phenylenediacetate and bis(imidazol-1-ylmethyl) benzene linkers:the effect of ligand isomers on the solid state structures [O] . Günay Sezer, Günes, Zafer Yesilel, Okan, Sahin, Onur, 2017

机译：含有苯二乙酸酯和双（咪唑-1-基甲基）苯接头的锌（II）和镉（II）配位聚合物：配体异构体对固态结构的影响

Three Topological Isomers of 1D-and 2D-Coordination Polymers Consisting of Tricopper Pyrazolate SBUs and 4,4 '-Trimethylenedipyridine Linkers: Effect of Pressure on the Structure

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