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Recoverable Mechanoresponsive Luminescent Molecular Sponge Material: A Novel Aryl Gold(I) Isocyanide Compound

机译:可恢复的力学函数发光分子海绵材料:一种新型芳基金(I)异氰化物化合物

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摘要

A novel aryl gold(I) isocyanide complex with reversible sponge mechanoresponsive luminescent (MRL) property is reported. Upon grinding, the green-emitting crystals (1g) converted to a yellow-emitting amorphous state (1y). There are two ways to achieve the reversible process: after placing 1y for 10 h at room temperature, an intermediate state was generated and then dichloromethane (DCM) was added; lg can be directly obtained by recrystallizing in DCM. The recovery is triggered by the weak halogen bonding and pi...pi stacking interactions.
机译:报道了一种新的芳基金(I)芳基金(I)异氰化物配合物,具有可逆海绵力学致光(MRL)性能。 在研磨时,将产生的绿色晶体(1g)转化为黄色发射非晶态(1Y)。 有两种方法可以实现可逆过程:在室温下放置10小时后,产生中间状态,然后加入二氯甲烷(DCM); LG可以通过在DCM中重结晶直接获得。 恢复由弱卤素键合和PI ... PI堆叠相互作用触发。

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  • 来源
    《Crystal growth & design》 |2019年第2期|共5页
  • 作者单位

    Zhengzhou Univ Coll Chem &

    Mol Engn Zhengzhou 450001 Henan Peoples R China;

    Zhengzhou Univ Coll Chem &

    Mol Engn Zhengzhou 450001 Henan Peoples R China;

    Zhengzhou Univ Coll Chem &

    Mol Engn Zhengzhou 450001 Henan Peoples R China;

    Nanyang Normal Univ Coll Chem &

    Pharmaceut Engn Nanyang 473061 Peoples R China;

    Nanyang Normal Univ Coll Chem &

    Pharmaceut Engn Nanyang 473061 Peoples R China;

    Zhengzhou Univ Coll Chem &

    Mol Engn Zhengzhou 450001 Henan Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 晶体学;
  • 关键词

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