An Unusual Mercury(II) Diisopropyldithiocarbamate Coordination Polymer

Angeloski Alexander; Rawal Aditya; Bhadbhade Mohan; Hook James M.; Schurko Robert W.; Mcdonagh Andrew M.

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An Unusual Mercury(II) Diisopropyldithiocarbamate Coordination Polymer

机译：不寻常的汞（II）二异丙二硫代氨基甲酸酯配位聚合物

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A new polymeric mercury(II) diisopropyldithiocarbamate complex was synthesized by the reaction of sodium diisopropyldithiocarbamate with excess HgCl2 in water. The precise structure of the new compound was determined by single-crystal X-ray diffraction. A similar reaction, using a stoichiometric excess of the ligand, yielded the known monomeric bis(diisopropyldithiocarbamato)mercury(II) complex. The complexes could not be distinguished from each other by their solution-phase NMR spectra or their FTIR spectra. Solid-state NMR spectroscopy (Hg-199 and C-13) provided unambiguous data and showed that the monomeric complex and polymeric complex do not interconvert in solution or during crystal growth. Thermogravimetric experiments revealed quite different thermal decomposition behavior between the two compounds.

机译：通过DiisOppopydithiocarbamate与水中过量的HgCl2在水中的反应合成了一种新的聚合物汞（II）二异丙二硫代氨基甲磺酸酯络合物。通过单晶X射线衍射测定新化合物的精确结构。使用化学计量过量的配体的类似反应得到了已知的单体双（DiisOppoptoldithiocarbamato）汞（II）络合物。通过其溶液相NMR光谱或其FTIR光谱不能彼此区分复合物。固态NMR光谱（HG-199和C-13）提供明确的数据，并显示单体复合物和聚合物复合物在溶液中或在晶体生长期间不互连。热重试验显示两种化合物之间的热分解行为相当不同。

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来源
《Crystal growth & design》 |2019年第2期|共9页
作者
Angeloski Alexander; Rawal Aditya; Bhadbhade Mohan; Hook James M.; Schurko Robert W.; Mcdonagh Andrew M.;
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作者单位

Univ Technol Sydney Sch Math &

Phys Sci Ultimo 2007 Australia;

Univ New South Wales NMR Facil Mark Wainwright Analyt Ctr Sydney NSW 2052 Australia;

Univ New South Wales Sch Chem Sydney NSW 2052 Australia;

Univ New South Wales NMR Facil Mark Wainwright Analyt Ctr Sydney NSW 2052 Australia;

Univ Windsor Dept Chem &

Biochem Windsor ON N9B 3P4 Canada;

Univ Technol Sydney Sch Math &

Phys Sci Ultimo 2007 Australia;

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正文语种 eng
中图分类晶体学;
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1. An Unusual Mercury(II) Diisopropyldithiocarbamate Coordination Polymer [J] . Angeloski Alexander, Rawal Aditya, Bhadbhade Mohan, Nature reviews Cancer . 2019,第2期

机译：不寻常的汞（II）二异丙二酸二氨基甲酸酯配位聚合物
2. In situ crystalline transformation of bis(halo)mercury(II) coordination polymers to ionic chloro-bridged-bis(halo)mercury(II) species via UV irradiation in chloroform media [J] . Choi Eunkyung, Lee Haeri, Noh Tae Hwan, CrystEngComm . 2016,第37期

机译：在氯仿介质中通过UV辐射将双（卤）汞（II）配位聚合物原位结晶转化为离子氯桥联双（卤）汞（II）物种
3. Synthesis, structure and luminescence behaviour of a mononuclear cadmium(II) dicyanamide and a coordination polymer of mercury(II) dicyanamide containing 2,2′-dipyridylamine (dpaH) as end-capping ligand/anion of dpaH as binucleating bridge. Variance in coordination numbers, nuclearities and architectures with metal ion templates [J] . Das S., Bhar K., Chantrapromma S., Inorganica Chimica Acta . 2011,第1期

机译：含2,2'-联吡啶胺（dpaH）作为端基配体/ dpaH阴离子为双核桥的单核镉（II）双氰胺和汞（II）双氰胺的配位聚合物的合成，结构和发光行为。金属离子模板在配位数，核数和结构方面的差异
4. Luminescence Properties of Organometallic/Coordination Oligomers and Polymers Containing Diphosphine and Diisocyanide Assembling Ligands: Comparison between Mononuclear Model Complexes and Polymers [C] . Pierre D. Harvey Macromolecular Symposia 209; Organometallic and Coordination Clusters and Polymers: Syntheses and Applications Symposium; 20040529-0601; London(CA) . 2004

机译：有机金属/配位低聚物和含二膦和二异氰酸酯组装配体的聚合物的发光性质：单核模型配合物和聚合物之间的比较。
5. Synthesis and Structural Characterization of Mercury(II) Coordination Polymers Based on 1,2,4,5-Tetra(Isopropylthio) Benzene Ligand [D] . Selby-Karney, Troy. 2018

机译：1,2,4,5-四（异丙硫基）苯配体的汞（II）配位聚合物的合成与结构表征
6. Crystal structure of an HgII coordination polymer with an unsymmetrical dipyridyl ligand: catena-polydichloridomercury(II)-μ-N-(pyridin-4-ylmethyl)pyridin-3-amine-κ2N:N′ chloroform hemisolvate [O] . Suk-Hee Moon, Donghyun Kang, Ki-Min Park 2016

机译：具有不对称二吡啶基配体的HgII配位聚合物的晶体结构：链状聚二氯亚甲基汞（II）-μ-N-（吡啶-4-基甲基基）吡啶-3-胺-κ2N：N氯仿半溶剂合物
7. An Unusual Mercury(II) Diisopropyldithiocarbamate Coordination Polymer [O] . -1

机译：不寻常的汞（II）二异丙二酸二氨基甲酸酯配位聚合物
8. Inorganic Coordination Polymers. VIII. Cobalt(II) and Zinc(II) Phosphinate Polymers and Copolymers. [R] . Rose, S. H., Block, B. P. 1965

机译：无机配位聚合物。八。钴（II）和锌（II）次膦酸盐聚合物和共聚物。

An Unusual Mercury(II) Diisopropyldithiocarbamate Coordination Polymer

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