Rational Design and Synthesis of Hexanuclear Rare Earth the-a Metal-Organic Frameworks Platform Based on RE6O4(OH)(4)(COO)(8) Clusters

Feng Yang; Xing Xuelian; Zhang Yue; Guo Bingbing; Li Fugang; Kong Xia; Wang Yijie; Wang Xia; Wang Yutong; Zhang Liangliang; Sun Daofeng

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Rational Design and Synthesis of Hexanuclear Rare Earth the-a Metal-Organic Frameworks Platform Based on RE6O4(OH)(4)(COO)(8) Clusters

机译：基于RE6O4（OH）（4）（COO）（8）簇的合理设计和合成己克核稀土 - 金属 - 有机框架平台

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A series of hexanuclear RE(III) metal-organic frameworks, UPC-68, with the-a topology, have been successfully designed and synthesized by topology guidance (RE = rare earths). It is worth mentioning that the synthetic RE(III)-MOFs are constructed by a stable D-4h 8-connected RE6 cluster, which is reported first, and a D-3h 3-connected ligand (H(3)CTTA). The results indicate that UPC-68-Tb shows the characteristic recognition of 4-nitroaniline (4-NA), 2-nitroaniline (2-NA), and 4-nitrophenol (4-NP), and iodine adsorption capacity.

机译：通过拓扑指导（RE =稀土）成功地设计和合成了一系列六核RE（III）金属 - 有机框架，UPC-68，拓扑结构，拓扑结构，并合成了拓扑结构（RE =稀土）。值得一提的是，合成RE（III）-MOFS由稳定的D-4H 8连接的RE6簇构成，其首先报道，以及D-3H 3连接的配体（H（3）CTTA）。结果表明，UPC-68-TB显示了4-硝基苯胺（4-Na），2-硝基苯胺（2-Na）和4-硝基苯酚（4-NP）和碘吸附能力的特征识别。

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来源
《Crystal growth & design》 |2019年第3期|共5页
作者
Feng Yang; Xing Xuelian; Zhang Yue; Guo Bingbing; Li Fugang; Kong Xia; Wang Yijie; Wang Xia; Wang Yutong; Zhang Liangliang; Sun Daofeng;
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作者单位

China Univ Petr East China Sch Mat Sci &

Engn Minist Educ Key Lab Unconvent Oil &

Gas Dev Qingdao 266580 Shandong Peoples R China;

Hebei Univ Minist Educ Coll Publ Hlth Baoding 071000 Peoples R China;

China Univ Petr East China Sch Mat Sci &

Engn Minist Educ Key Lab Unconvent Oil &

Gas Dev Qingdao 266580 Shandong Peoples R China;

China Univ Petr East China Sch Mat Sci &

Engn Minist Educ Key Lab Unconvent Oil &

Gas Dev Qingdao 266580 Shandong Peoples R China;

China Univ Petr East China Sch Mat Sci &

Engn Minist Educ Key Lab Unconvent Oil &

Gas Dev Qingdao 266580 Shandong Peoples R China;

Shandong Univ Sci &

Technol Sch Chem &

Environm Engn Qingdao 266510 Peoples R China;

China Univ Petr East China Sch Mat Sci &

Engn Minist Educ Key Lab Unconvent Oil &

Gas Dev Qingdao 266580 Shandong Peoples R China;

China Univ Petr East China Sch Mat Sci &

Engn Minist Educ Key Lab Unconvent Oil &

Gas Dev Qingdao 266580 Shandong Peoples R China;

China Univ Petr East China Sch Mat Sci &

Engn Minist Educ Key Lab Unconvent Oil &

Gas Dev Qingdao 266580 Shandong Peoples R China;

Northwestern Polytech Univ Inst Flexible Elect Xian 710072 Shaanxi Peoples R China;

China Univ Petr East China Sch Mat Sci &

Engn Minist Educ Key Lab Unconvent Oil &

Gas Dev Qingdao 266580 Shandong Peoples R China;

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正文语种 eng
中图分类晶体学;
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1. Rational Design and Synthesis of Hexanuclear Rare Earth the-a Metal-Organic Frameworks Platform Based on RE6O4(OH)(4)(COO)(8) Clusters [J] . Feng Yang, Xing Xuelian, Zhang Yue, Crystal growth & design . 2019,第3期

机译：基于RE6O4（OH）（4）（COO）（8）簇的合理设计和合成己克核稀土 - 金属 - 有机框架平台
2. Rare Earth pcu Metal-Organic Framework Platform Based on RE_4(μ3-OH)_4(COO)_6~(2+) Clusters: Rational Design, Directed Synthesis, and Deliberate Tuning of Excitation Wavelengths [J] . Tian-Yi Luo, Chong Liu, Svetlana V. Eliseeva, Journal of the American Chemical Society . 2017,第27期

机译：基于RE_4（μ3-OH）_4（COO）_6〜（2+）簇的稀土pcu金属有机框架平台：合理设计，定向合成和激发波长的故意调整
3. Reticular Chemistry and the Discovery of a New Family of Rare Earth (4,8)-Connected Metal-Organic Frameworks with csq Topology Based on RE4(mu(3)-O)(2)(COO)(8) Clusters [J] . Angeli Giasemi K., Sartsidou Christina, Vlachaki Styliani, ACS applied materials & interfaces . 2017,第51期

机译：网状化学和发现新的稀土系列（4,8）的基于RE4（MU（3）-O）（2）（COO）（8）集群的CSQ拓扑
4. Zeolites embrace metal-organic frameworks: building block approach to the design and synthesis of zeolite-like metal-organic frameworks (ZMOFs) [C] . Zehong Zhang, Fuyuan Liu, Yunwen Wang, 40th Anniversary of International Zeolite Conference;International Zeolite Conference . 2007

机译：沸石包含金属有机骨架：构造和合成类沸石金属有机骨架（ZMOF）的基础方法
5. Design, synthesis, characterization, and sorption properties of metal-organic frameworks and polyhedra based on [iron(3)oxide(R dioxide)(6)L(3)](0/+) clusters. [D] . Sudik, Andrea C. 2005

机译：设计，合成，表征，和基于[铁（3）氧化物（R二氧化）（6）L（3）]（0 / +）簇的多面体的吸附性能。
6. Versatile rare earth hexanuclear clusters for the design and synthesis of highly-connected ftw-MOFs [O] . Ryan Luebke, Youssef Belmabkhout, Łukasz J. Weseliński, 2015

机译：多功能稀土六核簇用于设计和合成高度连接的ftw-MOF
7. Frontispiece: Rational Design and Synthesis of a Highly Porous Copper-Based Interpenetrated Metal-Organic Framework for High CO2and H2Adsorption [O] . Purnandhu Bose, Linyi Bai, Rakhesh Ganguly, 2015

机译：正面：合理的设计和合成高CO2和H2吸附的高孔铜互进的金属 - 有机骨架

Rational Design and Synthesis of Hexanuclear Rare Earth the-a Metal-Organic Frameworks Platform Based on RE6O4(OH)(4)(COO)(8) Clusters

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