Rapid Synthesis of Hierarchical Porous Metal-Organic Frameworks and the Simulation of Growth

Zhang Hang; Huo Jinhao; Li Feier; Duan Chongxiong; Xi Hongxia

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Rapid Synthesis of Hierarchical Porous Metal-Organic Frameworks and the Simulation of Growth

机译：快速合成等级多孔金属 - 有机框架及其生长的模拟

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Hierarchically porous metal-organic frameworks (HP-MOFs) have been successfully synthesized under mild conditions within 60 s using an anionic surfactant in a (Cu, Zn) hydroxyl double salt (HDS) solution. The anionic surfactant served as a template for the construction of mesopores and macropores, and the (Cu, Zn) HDS accelerated crystal nucleation. Importantly, the growth of the HP-MOFs was monitored by attenuated total-reflectance Fourier-transform infrared spectroscopy, and the mechanism of synthesis was explored using mesodynamics (MesoDyn) simulations. The introduction of larger pores into conventional MOFs aided the diffusion of bulky molecules into the active center and enhanced the catalytic activity of the MOFs.

机译：在60秒内使用阴离子表面活性剂在60秒内成功地合成了层次的多孔金属 - 有机框架（HP-MOF）在（Cu，Zn）羟基双盐（HDS）溶液中，在60秒内成功地合成。阴离子表面活性剂用作构建中孔和大孔的模板，以及（Cu，Zn）HDS加速晶体成核。重要的是，通过减弱总反射率傅立叶变换红外光谱来监测HP-MOF的生长，使用Mesodynamics（Mesodyn）模拟探索合成机制。将较大的孔引入常规MOFS将庞大分子扩散到活性中心中并增强了MOF的催化活性。

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来源
《Crystal growth & design》 |2018年第11期|共9页
作者
Zhang Hang; Huo Jinhao; Li Feier; Duan Chongxiong; Xi Hongxia;
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作者单位

South China Univ Technol Sch Chem &

Chem Engn Guangzhou 510640 Guangdong Peoples R China;

South China Univ Technol Sch Chem &

Chem Engn Guangzhou 510640 Guangdong Peoples R China;

South China Univ Technol Sch Chem &

Chem Engn Guangzhou 510640 Guangdong Peoples R China;

South China Univ Technol Sch Chem &

Chem Engn Guangzhou 510640 Guangdong Peoples R China;

South China Univ Technol Sch Chem &

Chem Engn Guangzhou 510640 Guangdong Peoples R China;

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原文格式 PDF
正文语种 eng
中图分类晶体学;
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专利

1. Rapid Synthesis of Hierarchical Porous Metal-Organic Frameworks and the Simulation of Growth [J] . Zhang Hang, Huo Jinhao, Li Feier, Crystal growth & design . 2018,第11期

机译：快速合成等级多孔金属 - 有机框架及其生长的模拟
2. Rapid Synthesis of Hierarchical Porous Metal-Organic Frameworks and the Simulation of Growth [J] . Zhang Hang, Huo Jinhao, Li Feier, Crystal growth & design . 2018,第11期

机译：快速合成等级多孔金属 - 有机框架及其生长的模拟
3. Green and rapid preparation of hierarchically porous metal-organic zeolites and simulation of their growth [J] . Zhang Hang, Huo Jinhao, Yang Haiwu, Journal of Materials Chemistry, A. Materials for energy and sustainability . 2019,第3期

机译：阶级多孔金属 - 有机沸石的绿色和快速制备及其生长的模拟
4. (Invited) Defective Hierarchical Porous Copper-Based Metal-Organic Frameworks Synthesised Via Facile Acid Etching Strategy [C] . Huan Doan Pacific Rim Meeting on Electrochemical and Solid-State Science . 2020

机译：（被邀请的）通过容易酸蚀刻策略合成的分层多孔铜基金属有机骨架
5. Synthesis and gas adsorption study of porous metal-organic framework materials. [D] . Mu, Bin. 2011

机译：多孔金属有机骨架材料的合成及气体吸附研究。
6. Defective hierarchical porous copper-based metal-organic frameworks synthesised via facile acid etching strategy [O] . Huan V. Doan, Asel Sartbaeva, Jean-Charles Eloi, -1

机译：通过轻度酸腐蚀策略合成的有缺陷的分层多孔铜基金属有机骨架
7. Rapid Synthesis of Hierarchical Porous MetalOrganic Frameworks and the Simulation of Growth [O] . -1

机译：快速合成分层多孔金属框架和生长的模拟

Rapid Synthesis of Hierarchical Porous Metal-Organic Frameworks and the Simulation of Growth

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