Zone-Collapse Amorphization Mimicking the Negative Compressibility of a Porous Compound

Szymon Sobczak; Andrzej Katrusiak

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Zone-Collapse Amorphization Mimicking the Negative Compressibility of a Porous Compound

机译：区域折叠非晶模仿多孔化合物的负压缩性

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A strongly anisotropic architecture of stacked metal–organic grids, with pores arranged through their eyes, has been revealed for the new coordination polymer Ni(bipy)(hip)(H_(2)O)_(2)·DMF·CH_(3)OH·H_(2)O, where bipy is 4,4′-bipyridine and hip is 5-hydroxyisophthalic acid. This porous crystal, when submerged in various nonpenetrating oils used as the hydrostatic media, displays a negative volume compressibility. This counterintuitive effect results in the zone amorphization injecting the contents of collapsing pores into the retained crystalline portions of the sample. This additional contents of the pores supports the crystalline parts and prevents their amorphization.

机译：堆叠金属 - 有机栅格的强烈各向异性结构，具有通过其眼睛布置的孔，已揭示新的配位聚合物Ni（Bipy）（Hip）（H_（2）O）_（2）·DMF·CH_（3 ）哦当浸没在用作静水压介质的各种非旋转油中时，这种多孔晶体显示出负体压缩性。该反向效应导致区域非晶化将孔的含量注入样品的保留晶体部分中。孔的这种额外内容物支持结晶部分并防止它们的非晶化。

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《Crystal growth & design》 |2018年第2期|共8页
作者
Szymon Sobczak; Andrzej Katrusiak;
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Faculty of Chemistry Adam Mickiewicz University Umultowska 89b 61-614 Poznan Poland;

Faculty of Chemistry Adam Mickiewicz University Umultowska 89b 61-614 Poznan Poland;

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正文语种 eng
中图分类晶体学;
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1. Zone-Collapse Amorphization Mimicking the Negative Compressibility of a Porous Compound [J] . Szymon Sobczak, Andrzej Katrusiak Crystal growth & design . 2018,第2期

机译：区域折叠非晶模仿多孔化合物的负压缩性
2. Compressibility anomaly and amorphization in the anisotropic negative thermal expansion material NbOPO4 under pressure [J] . Mukherjee GD, Vijaykumar V, Karandikar AS, International Journal of Quantum Chemistry . 2005,第1期

机译：各向异性负热膨胀材料NbOPO4在压力下的压缩异常和非晶化
3. Spontaneous crystalline-to-amorphous phase transformation of organic or medicinal compounds in the presence of porous media, part 1: thermodynamics of spontaneous amorphization. [J] . Qian KK, Bogner RH Journal of pharmaceutical sciences. . 2011,第7期

机译：在多孔介质存在下有机或药用化合物的自发晶态至非晶态相变，第1部分：自发非晶化的热力学。
4. Design and fabrication of materials and structures with negative Poisson's ratio and negative linear compressibility [C] . Arash Ghaedizadeh, Jianhu Shen, Xin Ren, Conference on behavior and mechanics of multifunctional materials and composites . 2017

机译：具有负泊松比和负线性可压缩性的材料和结构的设计与制造
5. The amorphization of intermetallic compounds by mechanical alloying/milling [D] . Cho, Yoonsung 1991

机译：机械合金化/铣削使金属间化合物非晶化
6. Isothermal compressibility and isobaric thermal shrinkage of a porous α-alumina compact: thermodynamic calculations [O] . Yüksel SARIKAYA, Müşerref ÖNAL, Abdullah Devrim PEKDEMIR 2020

机译：多孔α-氧化铝紧凑型的等温可压缩性和异常热收缩：热力学计算
7. High-pressure guest-included phase transitions, amorphisation and negative linear compressibility on a porous copper-based metal organic framework [O] . Charlie J. McMonagle, Priyanka Comar, Euan K. Brechin, 2016

机译：多孔铜基金属有机框架上的高压客人纳入的相变，无孔和负线性可压缩性
8. Dynamics of radiation-induced amorphization in intermetallic compounds [R] . Lam, N Q, Okamoto, PR, Devanathan, R, 1992

机译：金属间化合物中辐射诱导非晶化的动力学

Zone-Collapse Amorphization Mimicking the Negative Compressibility of a Porous Compound

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